Crystal structure of [NiHg(SCN)(4)(CH(3)OH)(2)](n)

The title compound, catena-poly[[bis­(methanol-κO)nickel(II)]-di-μ-thio­cyanato-κ(4) N:S-mercurate(II)-di-μ-thio­cyanato-κ(4) N:S], was obtained from a gel-growth method using tetra­meth­oxy­silane as gelling agent. The crystal structure is composed of rather regular HgS(4) tetra­hedra (point group...

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Detalles Bibliográficos
Autores principales: Weil, Matthias, Häusler, Thomas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4158493/
https://www.ncbi.nlm.nih.gov/pubmed/25249851
http://dx.doi.org/10.1107/S1600536814009532
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author Weil, Matthias
Häusler, Thomas
author_facet Weil, Matthias
Häusler, Thomas
author_sort Weil, Matthias
collection PubMed
description The title compound, catena-poly[[bis­(methanol-κO)nickel(II)]-di-μ-thio­cyanato-κ(4) N:S-mercurate(II)-di-μ-thio­cyanato-κ(4) N:S], was obtained from a gel-growth method using tetra­meth­oxy­silane as gelling agent. The crystal structure is composed of rather regular HgS(4) tetra­hedra (point group symmetry .2.) and trans-NiN(4)O(2) octa­hedra (point group symmetry 2..) that are linked through thio­cyanato bridges into a three-dimensional framework. The methanol mol­ecules coordinate via the O atom to the Ni(2+) cations and point into the voids of this arrangement while a weak O—H⋯S hydrogen bond to an adjacent S atom stabilizes it.
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spelling pubmed-41584932014-09-23 Crystal structure of [NiHg(SCN)(4)(CH(3)OH)(2)](n) Weil, Matthias Häusler, Thomas Acta Crystallogr Sect E Struct Rep Online Research Communications The title compound, catena-poly[[bis­(methanol-κO)nickel(II)]-di-μ-thio­cyanato-κ(4) N:S-mercurate(II)-di-μ-thio­cyanato-κ(4) N:S], was obtained from a gel-growth method using tetra­meth­oxy­silane as gelling agent. The crystal structure is composed of rather regular HgS(4) tetra­hedra (point group symmetry .2.) and trans-NiN(4)O(2) octa­hedra (point group symmetry 2..) that are linked through thio­cyanato bridges into a three-dimensional framework. The methanol mol­ecules coordinate via the O atom to the Ni(2+) cations and point into the voids of this arrangement while a weak O—H⋯S hydrogen bond to an adjacent S atom stabilizes it. International Union of Crystallography 2014-07-19 /pmc/articles/PMC4158493/ /pubmed/25249851 http://dx.doi.org/10.1107/S1600536814009532 Text en © Weil and Häusler 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Weil, Matthias
Häusler, Thomas
Crystal structure of [NiHg(SCN)(4)(CH(3)OH)(2)](n)
title Crystal structure of [NiHg(SCN)(4)(CH(3)OH)(2)](n)
title_full Crystal structure of [NiHg(SCN)(4)(CH(3)OH)(2)](n)
title_fullStr Crystal structure of [NiHg(SCN)(4)(CH(3)OH)(2)](n)
title_full_unstemmed Crystal structure of [NiHg(SCN)(4)(CH(3)OH)(2)](n)
title_short Crystal structure of [NiHg(SCN)(4)(CH(3)OH)(2)](n)
title_sort crystal structure of [nihg(scn)(4)(ch(3)oh)(2)](n)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4158493/
https://www.ncbi.nlm.nih.gov/pubmed/25249851
http://dx.doi.org/10.1107/S1600536814009532
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AT hauslerthomas crystalstructureofnihgscn4ch3oh2n

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