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(Z)-2,3-Di­chloro-1,4-bis­(4-chloro­phen­yl)but-2-ene-1,4-dione

The title compound, C(16)H(8)Cl(4)O(2), crystallizes with two independent mol­ecules in the asymmetric unit. Both mol­ecules have a Z conformation around the central double bond and they show significantly different C—C—C—O torsion angles between the aromatic ring and the carbonyl group [30.1 (7) an...

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Detalles Bibliográficos
Autores principales: Tittal, Ram K., Kumar, Satish, Ram, R. N.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4158494/
https://www.ncbi.nlm.nih.gov/pubmed/25249911
http://dx.doi.org/10.1107/S1600536814015463
Descripción
Sumario:The title compound, C(16)H(8)Cl(4)O(2), crystallizes with two independent mol­ecules in the asymmetric unit. Both mol­ecules have a Z conformation around the central double bond and they show significantly different C—C—C—O torsion angles between the aromatic ring and the carbonyl group [30.1 (7) and 3.9 (7)° in one molecule and 23.5 (7) and 9.3 (8)° in the other]. The crystal packing shows short halogen Cl⋯O [3.003 (5) and 3.246 (4) Å] and Cl⋯Cl [3.452 (2) Å] contacts and aromatic C—H⋯Cl and C—H⋯O inter­actions link the molecules, resulting in chains propogating along [100]. The crystal structure also features π–π stacking inter­actions between aromatic units of the two independent mol­ecules, with a centroid–centroid distance of 3.9264 (6) Å.