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3,10,14,21-Tetra­kis(4-meth­oxy­phen­yl)penta­cyclo­[11.8.0.0(2,11).0(4,9).0(15,20)]henicosa-1(21),2,4(9),5,7,10,13,15(20),16,18-decaen-12-one chloro­form monosolvate

The asymmetric unit of the title compound, C(49)H(36)O(6)·CHCl(3), contains half an organic mol­ecule, the complete mol­ecule being generated by the operation of a crystallographic twofold rotation axis, and half a highly disordered chloro­form mol­ecule. The contribution to the diffraction pattern...

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Autores principales: Gopinath, S., Narayanan, P., Sethusankar, K., Nandakumar, Meganathan, Mohanakrishnan, Arasambattu K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4158498/
https://www.ncbi.nlm.nih.gov/pubmed/25249919
http://dx.doi.org/10.1107/S1600536814016389
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author Gopinath, S.
Narayanan, P.
Sethusankar, K.
Nandakumar, Meganathan
Mohanakrishnan, Arasambattu K.
author_facet Gopinath, S.
Narayanan, P.
Sethusankar, K.
Nandakumar, Meganathan
Mohanakrishnan, Arasambattu K.
author_sort Gopinath, S.
collection PubMed
description The asymmetric unit of the title compound, C(49)H(36)O(6)·CHCl(3), contains half an organic mol­ecule, the complete mol­ecule being generated by the operation of a crystallographic twofold rotation axis, and half a highly disordered chloro­form mol­ecule. The contribution to the diffraction pattern of the latter was removed using the program SQUEEZE in PLATON [Spek (2009 ▶). Acta Cryst. D65, 148–155]; the unit-cell characteristics take into account the presence of CHCl(3). The dihedral angles between the planes of the naphthalene ring system and the meth­oxy­benzene rings are 71.05 (7) (syn to the central C=O group) and 57.27 (6)° (anti to the central C=O group). In the crystal, mol­ecules are linked by C—H⋯O inter­actions, generating C(12) chains running parallel to the b axis.
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spelling pubmed-41584982014-09-23 3,10,14,21-Tetra­kis(4-meth­oxy­phen­yl)penta­cyclo­[11.8.0.0(2,11).0(4,9).0(15,20)]henicosa-1(21),2,4(9),5,7,10,13,15(20),16,18-decaen-12-one chloro­form monosolvate Gopinath, S. Narayanan, P. Sethusankar, K. Nandakumar, Meganathan Mohanakrishnan, Arasambattu K. Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(49)H(36)O(6)·CHCl(3), contains half an organic mol­ecule, the complete mol­ecule being generated by the operation of a crystallographic twofold rotation axis, and half a highly disordered chloro­form mol­ecule. The contribution to the diffraction pattern of the latter was removed using the program SQUEEZE in PLATON [Spek (2009 ▶). Acta Cryst. D65, 148–155]; the unit-cell characteristics take into account the presence of CHCl(3). The dihedral angles between the planes of the naphthalene ring system and the meth­oxy­benzene rings are 71.05 (7) (syn to the central C=O group) and 57.27 (6)° (anti to the central C=O group). In the crystal, mol­ecules are linked by C—H⋯O inter­actions, generating C(12) chains running parallel to the b axis. International Union of Crystallography 2014-07-23 /pmc/articles/PMC4158498/ /pubmed/25249919 http://dx.doi.org/10.1107/S1600536814016389 Text en © Gopinath et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Gopinath, S.
Narayanan, P.
Sethusankar, K.
Nandakumar, Meganathan
Mohanakrishnan, Arasambattu K.
3,10,14,21-Tetra­kis(4-meth­oxy­phen­yl)penta­cyclo­[11.8.0.0(2,11).0(4,9).0(15,20)]henicosa-1(21),2,4(9),5,7,10,13,15(20),16,18-decaen-12-one chloro­form monosolvate
title 3,10,14,21-Tetra­kis(4-meth­oxy­phen­yl)penta­cyclo­[11.8.0.0(2,11).0(4,9).0(15,20)]henicosa-1(21),2,4(9),5,7,10,13,15(20),16,18-decaen-12-one chloro­form monosolvate
title_full 3,10,14,21-Tetra­kis(4-meth­oxy­phen­yl)penta­cyclo­[11.8.0.0(2,11).0(4,9).0(15,20)]henicosa-1(21),2,4(9),5,7,10,13,15(20),16,18-decaen-12-one chloro­form monosolvate
title_fullStr 3,10,14,21-Tetra­kis(4-meth­oxy­phen­yl)penta­cyclo­[11.8.0.0(2,11).0(4,9).0(15,20)]henicosa-1(21),2,4(9),5,7,10,13,15(20),16,18-decaen-12-one chloro­form monosolvate
title_full_unstemmed 3,10,14,21-Tetra­kis(4-meth­oxy­phen­yl)penta­cyclo­[11.8.0.0(2,11).0(4,9).0(15,20)]henicosa-1(21),2,4(9),5,7,10,13,15(20),16,18-decaen-12-one chloro­form monosolvate
title_short 3,10,14,21-Tetra­kis(4-meth­oxy­phen­yl)penta­cyclo­[11.8.0.0(2,11).0(4,9).0(15,20)]henicosa-1(21),2,4(9),5,7,10,13,15(20),16,18-decaen-12-one chloro­form monosolvate
title_sort 3,10,14,21-tetra­kis(4-meth­oxy­phen­yl)penta­cyclo­[11.8.0.0(2,11).0(4,9).0(15,20)]henicosa-1(21),2,4(9),5,7,10,13,15(20),16,18-decaen-12-one chloro­form monosolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4158498/
https://www.ncbi.nlm.nih.gov/pubmed/25249919
http://dx.doi.org/10.1107/S1600536814016389
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