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3,10,14,21-Tetrakis(4-methoxyphenyl)pentacyclo[11.8.0.0(2,11).0(4,9).0(15,20)]henicosa-1(21),2,4(9),5,7,10,13,15(20),16,18-decaen-12-one chloroform monosolvate
The asymmetric unit of the title compound, C(49)H(36)O(6)·CHCl(3), contains half an organic molecule, the complete molecule being generated by the operation of a crystallographic twofold rotation axis, and half a highly disordered chloroform molecule. The contribution to the diffraction pattern...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4158498/ https://www.ncbi.nlm.nih.gov/pubmed/25249919 http://dx.doi.org/10.1107/S1600536814016389 |
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author | Gopinath, S. Narayanan, P. Sethusankar, K. Nandakumar, Meganathan Mohanakrishnan, Arasambattu K. |
author_facet | Gopinath, S. Narayanan, P. Sethusankar, K. Nandakumar, Meganathan Mohanakrishnan, Arasambattu K. |
author_sort | Gopinath, S. |
collection | PubMed |
description | The asymmetric unit of the title compound, C(49)H(36)O(6)·CHCl(3), contains half an organic molecule, the complete molecule being generated by the operation of a crystallographic twofold rotation axis, and half a highly disordered chloroform molecule. The contribution to the diffraction pattern of the latter was removed using the program SQUEEZE in PLATON [Spek (2009 ▶). Acta Cryst. D65, 148–155]; the unit-cell characteristics take into account the presence of CHCl(3). The dihedral angles between the planes of the naphthalene ring system and the methoxybenzene rings are 71.05 (7) (syn to the central C=O group) and 57.27 (6)° (anti to the central C=O group). In the crystal, molecules are linked by C—H⋯O interactions, generating C(12) chains running parallel to the b axis. |
format | Online Article Text |
id | pubmed-4158498 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-41584982014-09-23 3,10,14,21-Tetrakis(4-methoxyphenyl)pentacyclo[11.8.0.0(2,11).0(4,9).0(15,20)]henicosa-1(21),2,4(9),5,7,10,13,15(20),16,18-decaen-12-one chloroform monosolvate Gopinath, S. Narayanan, P. Sethusankar, K. Nandakumar, Meganathan Mohanakrishnan, Arasambattu K. Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(49)H(36)O(6)·CHCl(3), contains half an organic molecule, the complete molecule being generated by the operation of a crystallographic twofold rotation axis, and half a highly disordered chloroform molecule. The contribution to the diffraction pattern of the latter was removed using the program SQUEEZE in PLATON [Spek (2009 ▶). Acta Cryst. D65, 148–155]; the unit-cell characteristics take into account the presence of CHCl(3). The dihedral angles between the planes of the naphthalene ring system and the methoxybenzene rings are 71.05 (7) (syn to the central C=O group) and 57.27 (6)° (anti to the central C=O group). In the crystal, molecules are linked by C—H⋯O interactions, generating C(12) chains running parallel to the b axis. International Union of Crystallography 2014-07-23 /pmc/articles/PMC4158498/ /pubmed/25249919 http://dx.doi.org/10.1107/S1600536814016389 Text en © Gopinath et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Gopinath, S. Narayanan, P. Sethusankar, K. Nandakumar, Meganathan Mohanakrishnan, Arasambattu K. 3,10,14,21-Tetrakis(4-methoxyphenyl)pentacyclo[11.8.0.0(2,11).0(4,9).0(15,20)]henicosa-1(21),2,4(9),5,7,10,13,15(20),16,18-decaen-12-one chloroform monosolvate |
title | 3,10,14,21-Tetrakis(4-methoxyphenyl)pentacyclo[11.8.0.0(2,11).0(4,9).0(15,20)]henicosa-1(21),2,4(9),5,7,10,13,15(20),16,18-decaen-12-one chloroform monosolvate |
title_full | 3,10,14,21-Tetrakis(4-methoxyphenyl)pentacyclo[11.8.0.0(2,11).0(4,9).0(15,20)]henicosa-1(21),2,4(9),5,7,10,13,15(20),16,18-decaen-12-one chloroform monosolvate |
title_fullStr | 3,10,14,21-Tetrakis(4-methoxyphenyl)pentacyclo[11.8.0.0(2,11).0(4,9).0(15,20)]henicosa-1(21),2,4(9),5,7,10,13,15(20),16,18-decaen-12-one chloroform monosolvate |
title_full_unstemmed | 3,10,14,21-Tetrakis(4-methoxyphenyl)pentacyclo[11.8.0.0(2,11).0(4,9).0(15,20)]henicosa-1(21),2,4(9),5,7,10,13,15(20),16,18-decaen-12-one chloroform monosolvate |
title_short | 3,10,14,21-Tetrakis(4-methoxyphenyl)pentacyclo[11.8.0.0(2,11).0(4,9).0(15,20)]henicosa-1(21),2,4(9),5,7,10,13,15(20),16,18-decaen-12-one chloroform monosolvate |
title_sort | 3,10,14,21-tetrakis(4-methoxyphenyl)pentacyclo[11.8.0.0(2,11).0(4,9).0(15,20)]henicosa-1(21),2,4(9),5,7,10,13,15(20),16,18-decaen-12-one chloroform monosolvate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4158498/ https://www.ncbi.nlm.nih.gov/pubmed/25249919 http://dx.doi.org/10.1107/S1600536814016389 |
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