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Crystal structure of bis­{2-[(E)-(4-meth­oxy­lbenz­yl)imino­meth­yl]phenolato-κ(2) N,O (1)}nickel(II)

The asymmetric unit of the title compound, [Ni(C(15)H(14)NO(2))(2)], comprises an Ni(II) cation, lying on an inversion centre, and a Schiff base anion that acts as a bidentate ligand. The Ni(II) cation is in a square-planar coordination environment binding to the imine N and phenolate O atoms of the...

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Detalles Bibliográficos
Autores principales: Bahron, Hadariah, Tajuddin, Amalina Mohd, Ibrahim, Wan Nazihah Wan, Fun, Hoong-Kun, Chantrapromma, Suchada
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4158500/
https://www.ncbi.nlm.nih.gov/pubmed/25249867
http://dx.doi.org/10.1107/S160053681401650X
Descripción
Sumario:The asymmetric unit of the title compound, [Ni(C(15)H(14)NO(2))(2)], comprises an Ni(II) cation, lying on an inversion centre, and a Schiff base anion that acts as a bidentate ligand. The Ni(II) cation is in a square-planar coordination environment binding to the imine N and phenolate O atoms of the two Schiff base ligands. The N- and O-donor atoms of the two ligands are mutually trans, with Ni—N and Ni—O bond lengths of 1.9191 (11) and 1.8407 (9) Å, respectively. The plane of the meth­oxy­benzene ring makes a dihedral angle of 84.92 (6)° with that of the phenolate ring. In the crystal, mol­ecules are linked into screw chains by weak C—H⋯O hydrogen bonds. Additional C—H⋯O hydrogen bonds, together with C—H⋯π contacts, arrange the mol­ecules into sheets parallel to the ac plane.