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Crystal structure of bis­{2-[(E)-(4-meth­oxy­lbenz­yl)imino­meth­yl]phenolato-κ(2) N,O (1)}nickel(II)

The asymmetric unit of the title compound, [Ni(C(15)H(14)NO(2))(2)], comprises an Ni(II) cation, lying on an inversion centre, and a Schiff base anion that acts as a bidentate ligand. The Ni(II) cation is in a square-planar coordination environment binding to the imine N and phenolate O atoms of the...

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Autores principales: Bahron, Hadariah, Tajuddin, Amalina Mohd, Ibrahim, Wan Nazihah Wan, Fun, Hoong-Kun, Chantrapromma, Suchada
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4158500/
https://www.ncbi.nlm.nih.gov/pubmed/25249867
http://dx.doi.org/10.1107/S160053681401650X
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author Bahron, Hadariah
Tajuddin, Amalina Mohd
Ibrahim, Wan Nazihah Wan
Fun, Hoong-Kun
Chantrapromma, Suchada
author_facet Bahron, Hadariah
Tajuddin, Amalina Mohd
Ibrahim, Wan Nazihah Wan
Fun, Hoong-Kun
Chantrapromma, Suchada
author_sort Bahron, Hadariah
collection PubMed
description The asymmetric unit of the title compound, [Ni(C(15)H(14)NO(2))(2)], comprises an Ni(II) cation, lying on an inversion centre, and a Schiff base anion that acts as a bidentate ligand. The Ni(II) cation is in a square-planar coordination environment binding to the imine N and phenolate O atoms of the two Schiff base ligands. The N- and O-donor atoms of the two ligands are mutually trans, with Ni—N and Ni—O bond lengths of 1.9191 (11) and 1.8407 (9) Å, respectively. The plane of the meth­oxy­benzene ring makes a dihedral angle of 84.92 (6)° with that of the phenolate ring. In the crystal, mol­ecules are linked into screw chains by weak C—H⋯O hydrogen bonds. Additional C—H⋯O hydrogen bonds, together with C—H⋯π contacts, arrange the mol­ecules into sheets parallel to the ac plane.
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spelling pubmed-41585002014-09-23 Crystal structure of bis­{2-[(E)-(4-meth­oxy­lbenz­yl)imino­meth­yl]phenolato-κ(2) N,O (1)}nickel(II) Bahron, Hadariah Tajuddin, Amalina Mohd Ibrahim, Wan Nazihah Wan Fun, Hoong-Kun Chantrapromma, Suchada Acta Crystallogr Sect E Struct Rep Online Research Communications The asymmetric unit of the title compound, [Ni(C(15)H(14)NO(2))(2)], comprises an Ni(II) cation, lying on an inversion centre, and a Schiff base anion that acts as a bidentate ligand. The Ni(II) cation is in a square-planar coordination environment binding to the imine N and phenolate O atoms of the two Schiff base ligands. The N- and O-donor atoms of the two ligands are mutually trans, with Ni—N and Ni—O bond lengths of 1.9191 (11) and 1.8407 (9) Å, respectively. The plane of the meth­oxy­benzene ring makes a dihedral angle of 84.92 (6)° with that of the phenolate ring. In the crystal, mol­ecules are linked into screw chains by weak C—H⋯O hydrogen bonds. Additional C—H⋯O hydrogen bonds, together with C—H⋯π contacts, arrange the mol­ecules into sheets parallel to the ac plane. International Union of Crystallography 2014-07-23 /pmc/articles/PMC4158500/ /pubmed/25249867 http://dx.doi.org/10.1107/S160053681401650X Text en © Bahron et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Bahron, Hadariah
Tajuddin, Amalina Mohd
Ibrahim, Wan Nazihah Wan
Fun, Hoong-Kun
Chantrapromma, Suchada
Crystal structure of bis­{2-[(E)-(4-meth­oxy­lbenz­yl)imino­meth­yl]phenolato-κ(2) N,O (1)}nickel(II)
title Crystal structure of bis­{2-[(E)-(4-meth­oxy­lbenz­yl)imino­meth­yl]phenolato-κ(2) N,O (1)}nickel(II)
title_full Crystal structure of bis­{2-[(E)-(4-meth­oxy­lbenz­yl)imino­meth­yl]phenolato-κ(2) N,O (1)}nickel(II)
title_fullStr Crystal structure of bis­{2-[(E)-(4-meth­oxy­lbenz­yl)imino­meth­yl]phenolato-κ(2) N,O (1)}nickel(II)
title_full_unstemmed Crystal structure of bis­{2-[(E)-(4-meth­oxy­lbenz­yl)imino­meth­yl]phenolato-κ(2) N,O (1)}nickel(II)
title_short Crystal structure of bis­{2-[(E)-(4-meth­oxy­lbenz­yl)imino­meth­yl]phenolato-κ(2) N,O (1)}nickel(II)
title_sort crystal structure of bis­{2-[(e)-(4-meth­oxy­lbenz­yl)imino­meth­yl]phenolato-κ(2) n,o (1)}nickel(ii)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4158500/
https://www.ncbi.nlm.nih.gov/pubmed/25249867
http://dx.doi.org/10.1107/S160053681401650X
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