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Crystal structure of bis{2-[(E)-(4-methoxylbenzyl)iminomethyl]phenolato-κ(2) N,O (1)}nickel(II)
The asymmetric unit of the title compound, [Ni(C(15)H(14)NO(2))(2)], comprises an Ni(II) cation, lying on an inversion centre, and a Schiff base anion that acts as a bidentate ligand. The Ni(II) cation is in a square-planar coordination environment binding to the imine N and phenolate O atoms of the...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4158500/ https://www.ncbi.nlm.nih.gov/pubmed/25249867 http://dx.doi.org/10.1107/S160053681401650X |
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author | Bahron, Hadariah Tajuddin, Amalina Mohd Ibrahim, Wan Nazihah Wan Fun, Hoong-Kun Chantrapromma, Suchada |
author_facet | Bahron, Hadariah Tajuddin, Amalina Mohd Ibrahim, Wan Nazihah Wan Fun, Hoong-Kun Chantrapromma, Suchada |
author_sort | Bahron, Hadariah |
collection | PubMed |
description | The asymmetric unit of the title compound, [Ni(C(15)H(14)NO(2))(2)], comprises an Ni(II) cation, lying on an inversion centre, and a Schiff base anion that acts as a bidentate ligand. The Ni(II) cation is in a square-planar coordination environment binding to the imine N and phenolate O atoms of the two Schiff base ligands. The N- and O-donor atoms of the two ligands are mutually trans, with Ni—N and Ni—O bond lengths of 1.9191 (11) and 1.8407 (9) Å, respectively. The plane of the methoxybenzene ring makes a dihedral angle of 84.92 (6)° with that of the phenolate ring. In the crystal, molecules are linked into screw chains by weak C—H⋯O hydrogen bonds. Additional C—H⋯O hydrogen bonds, together with C—H⋯π contacts, arrange the molecules into sheets parallel to the ac plane. |
format | Online Article Text |
id | pubmed-4158500 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-41585002014-09-23 Crystal structure of bis{2-[(E)-(4-methoxylbenzyl)iminomethyl]phenolato-κ(2) N,O (1)}nickel(II) Bahron, Hadariah Tajuddin, Amalina Mohd Ibrahim, Wan Nazihah Wan Fun, Hoong-Kun Chantrapromma, Suchada Acta Crystallogr Sect E Struct Rep Online Research Communications The asymmetric unit of the title compound, [Ni(C(15)H(14)NO(2))(2)], comprises an Ni(II) cation, lying on an inversion centre, and a Schiff base anion that acts as a bidentate ligand. The Ni(II) cation is in a square-planar coordination environment binding to the imine N and phenolate O atoms of the two Schiff base ligands. The N- and O-donor atoms of the two ligands are mutually trans, with Ni—N and Ni—O bond lengths of 1.9191 (11) and 1.8407 (9) Å, respectively. The plane of the methoxybenzene ring makes a dihedral angle of 84.92 (6)° with that of the phenolate ring. In the crystal, molecules are linked into screw chains by weak C—H⋯O hydrogen bonds. Additional C—H⋯O hydrogen bonds, together with C—H⋯π contacts, arrange the molecules into sheets parallel to the ac plane. International Union of Crystallography 2014-07-23 /pmc/articles/PMC4158500/ /pubmed/25249867 http://dx.doi.org/10.1107/S160053681401650X Text en © Bahron et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Research Communications Bahron, Hadariah Tajuddin, Amalina Mohd Ibrahim, Wan Nazihah Wan Fun, Hoong-Kun Chantrapromma, Suchada Crystal structure of bis{2-[(E)-(4-methoxylbenzyl)iminomethyl]phenolato-κ(2) N,O (1)}nickel(II) |
title | Crystal structure of bis{2-[(E)-(4-methoxylbenzyl)iminomethyl]phenolato-κ(2)
N,O
(1)}nickel(II) |
title_full | Crystal structure of bis{2-[(E)-(4-methoxylbenzyl)iminomethyl]phenolato-κ(2)
N,O
(1)}nickel(II) |
title_fullStr | Crystal structure of bis{2-[(E)-(4-methoxylbenzyl)iminomethyl]phenolato-κ(2)
N,O
(1)}nickel(II) |
title_full_unstemmed | Crystal structure of bis{2-[(E)-(4-methoxylbenzyl)iminomethyl]phenolato-κ(2)
N,O
(1)}nickel(II) |
title_short | Crystal structure of bis{2-[(E)-(4-methoxylbenzyl)iminomethyl]phenolato-κ(2)
N,O
(1)}nickel(II) |
title_sort | crystal structure of bis{2-[(e)-(4-methoxylbenzyl)iminomethyl]phenolato-κ(2)
n,o
(1)}nickel(ii) |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4158500/ https://www.ncbi.nlm.nih.gov/pubmed/25249867 http://dx.doi.org/10.1107/S160053681401650X |
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