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Crystal structure of 4-methyl­sulfanyl-2-phenyl­quinazoline

In the title compound, C(15)H(12)N(2)S, the methylthioquinazoline group is planar with the methyl C displaced by only 0.116 (3) Å from the plane of the quinazoline moiety. The dihedral angle between the phenyl ring and the quinazoline ring system is 13.95 (5)°. In the crystal, each molecule is linke...

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Detalles Bibliográficos
Autores principales: Alshammari, Mohammed B., Smith, Keith, Hegazy, Amany S., Kariuki, Benson M., El-Hiti, Gamal A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4158504/
https://www.ncbi.nlm.nih.gov/pubmed/25249928
http://dx.doi.org/10.1107/S1600536814015657
Descripción
Sumario:In the title compound, C(15)H(12)N(2)S, the methylthioquinazoline group is planar with the methyl C displaced by only 0.116 (3) Å from the plane of the quinazoline moiety. The dihedral angle between the phenyl ring and the quinazoline ring system is 13.95 (5)°. In the crystal, each molecule is linked by π–π stacking between to two adjacent inversion-related molecules. On one side, the inverted quinazoline groups interact with a centroid–centroid distance of 3.7105 (9) Å. On the other side, the quinazoline group interacts with the pyrimidine and phenyl rings of the second neighbour with centroid–centroid distances of 3.5287 (8) and 3.8601 (9) Å, respectively.