(Benzyl­diphenyl­phosphane-1κP)[μ-bis(diphenylphosphan­yl)methane-2:3κ(2) P:P′]nona­carbonyl-1κ(3) C,2κ(3) C,3κ(3) C-triangulo-triruthenium(0)

The asymmetric unit of the title compound, [Ru(3)(C(19)H(17)P)(C(25)H(22)P(2))(CO)(9)], consists of two independent mol­ecules. The bis­(di­phenyl­phosphan­yl)methane ligand bridges an Ru—Ru bond and the benzyl­diphenyl­phosphane ligand binds to the third Ru atom. The Ru—Ru bond cis to the benzyl­di...

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Detalles Bibliográficos
Autores principales: Shawkataly, Omar bin, Khan, Imthyaz Ahmed, Sirat, Siti Syaida, Rosli, Mohd Mustaqim
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4158507/
https://www.ncbi.nlm.nih.gov/pubmed/25249878
http://dx.doi.org/10.1107/S1600536814015475
Descripción
Sumario:The asymmetric unit of the title compound, [Ru(3)(C(19)H(17)P)(C(25)H(22)P(2))(CO)(9)], consists of two independent mol­ecules. The bis­(di­phenyl­phosphan­yl)methane ligand bridges an Ru—Ru bond and the benzyl­diphenyl­phosphane ligand binds to the third Ru atom. The Ru—Ru bond cis to the benzyl­diphenyl­phosphane ligand is the longest of the three Ru—Ru bonds in both mol­ecules. In the crystal, mol­ecules are linked by C—H⋯O hydrogen bonds, forming layers parallel to the ac plane. C—H⋯π contacts further stabilize the crystal packing.

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