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(Benzyldiphenylphosphane-1κP)[μ-bis(diphenylphosphanyl)methane-2:3κ(2) P:P′]nonacarbonyl-1κ(3) C,2κ(3) C,3κ(3) C-triangulo-triruthenium(0)
The asymmetric unit of the title compound, [Ru(3)(C(19)H(17)P)(C(25)H(22)P(2))(CO)(9)], consists of two independent molecules. The bis(diphenylphosphanyl)methane ligand bridges an Ru—Ru bond and the benzyldiphenylphosphane ligand binds to the third Ru atom. The Ru—Ru bond cis to the benzyldi...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2014
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4158507/ https://www.ncbi.nlm.nih.gov/pubmed/25249878 http://dx.doi.org/10.1107/S1600536814015475 |
| _version_ | 1782334061911474176 |
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| author | Shawkataly, Omar bin Khan, Imthyaz Ahmed Sirat, Siti Syaida Rosli, Mohd Mustaqim |
| author_facet | Shawkataly, Omar bin Khan, Imthyaz Ahmed Sirat, Siti Syaida Rosli, Mohd Mustaqim |
| author_sort | Shawkataly, Omar bin |
| collection | PubMed |
| description | The asymmetric unit of the title compound, [Ru(3)(C(19)H(17)P)(C(25)H(22)P(2))(CO)(9)], consists of two independent molecules. The bis(diphenylphosphanyl)methane ligand bridges an Ru—Ru bond and the benzyldiphenylphosphane ligand binds to the third Ru atom. The Ru—Ru bond cis to the benzyldiphenylphosphane ligand is the longest of the three Ru—Ru bonds in both molecules. In the crystal, molecules are linked by C—H⋯O hydrogen bonds, forming layers parallel to the ac plane. C—H⋯π contacts further stabilize the crystal packing. |
| format | Online Article Text |
| id | pubmed-4158507 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2014 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-41585072014-09-23 (Benzyldiphenylphosphane-1κP)[μ-bis(diphenylphosphanyl)methane-2:3κ(2) P:P′]nonacarbonyl-1κ(3) C,2κ(3) C,3κ(3) C-triangulo-triruthenium(0) Shawkataly, Omar bin Khan, Imthyaz Ahmed Sirat, Siti Syaida Rosli, Mohd Mustaqim Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Ru(3)(C(19)H(17)P)(C(25)H(22)P(2))(CO)(9)], consists of two independent molecules. The bis(diphenylphosphanyl)methane ligand bridges an Ru—Ru bond and the benzyldiphenylphosphane ligand binds to the third Ru atom. The Ru—Ru bond cis to the benzyldiphenylphosphane ligand is the longest of the three Ru—Ru bonds in both molecules. In the crystal, molecules are linked by C—H⋯O hydrogen bonds, forming layers parallel to the ac plane. C—H⋯π contacts further stabilize the crystal packing. International Union of Crystallography 2014-07-11 /pmc/articles/PMC4158507/ /pubmed/25249878 http://dx.doi.org/10.1107/S1600536814015475 Text en © Shawkataly et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Shawkataly, Omar bin Khan, Imthyaz Ahmed Sirat, Siti Syaida Rosli, Mohd Mustaqim (Benzyldiphenylphosphane-1κP)[μ-bis(diphenylphosphanyl)methane-2:3κ(2) P:P′]nonacarbonyl-1κ(3) C,2κ(3) C,3κ(3) C-triangulo-triruthenium(0) |
| title | (Benzyldiphenylphosphane-1κP)[μ-bis(diphenylphosphanyl)methane-2:3κ(2)
P:P′]nonacarbonyl-1κ(3)
C,2κ(3)
C,3κ(3)
C-triangulo-triruthenium(0) |
| title_full | (Benzyldiphenylphosphane-1κP)[μ-bis(diphenylphosphanyl)methane-2:3κ(2)
P:P′]nonacarbonyl-1κ(3)
C,2κ(3)
C,3κ(3)
C-triangulo-triruthenium(0) |
| title_fullStr | (Benzyldiphenylphosphane-1κP)[μ-bis(diphenylphosphanyl)methane-2:3κ(2)
P:P′]nonacarbonyl-1κ(3)
C,2κ(3)
C,3κ(3)
C-triangulo-triruthenium(0) |
| title_full_unstemmed | (Benzyldiphenylphosphane-1κP)[μ-bis(diphenylphosphanyl)methane-2:3κ(2)
P:P′]nonacarbonyl-1κ(3)
C,2κ(3)
C,3κ(3)
C-triangulo-triruthenium(0) |
| title_short | (Benzyldiphenylphosphane-1κP)[μ-bis(diphenylphosphanyl)methane-2:3κ(2)
P:P′]nonacarbonyl-1κ(3)
C,2κ(3)
C,3κ(3)
C-triangulo-triruthenium(0) |
| title_sort | (benzyldiphenylphosphane-1κp)[μ-bis(diphenylphosphanyl)methane-2:3κ(2)
p:p′]nonacarbonyl-1κ(3)
c,2κ(3)
c,3κ(3)
c-triangulo-triruthenium(0) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4158507/ https://www.ncbi.nlm.nih.gov/pubmed/25249878 http://dx.doi.org/10.1107/S1600536814015475 |
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