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Isopropyl 1-benzoyl-4-benzoyloxy-2,6-diphenyl-1,2,3,6-tetrahydropyridine-3-carboxylate
In the title compound, C(35)H(31)NO(5), the piperidine ring has an envelope conformation, with the phenyl-substituted C atom adjacent to the methylene C atom as the flap. This flap atom deviates by 0.633 (2) Å from the mean plane of the other five essentially coplanar atoms in the ring (r.m.s. devi...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4158511/ https://www.ncbi.nlm.nih.gov/pubmed/25249905 http://dx.doi.org/10.1107/S1600536814015244 |
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author | Govindan, E. Murugavel, K. Amirthaganesan, S. SubbiahPandi, A. |
author_facet | Govindan, E. Murugavel, K. Amirthaganesan, S. SubbiahPandi, A. |
author_sort | Govindan, E. |
collection | PubMed |
description | In the title compound, C(35)H(31)NO(5), the piperidine ring has an envelope conformation, with the phenyl-substituted C atom adjacent to the methylene C atom as the flap. This flap atom deviates by 0.633 (2) Å from the mean plane of the other five essentially coplanar atoms in the ring (r.m.s. deviation = 0.044 Å). Intramolecular C—H⋯O hydrogen bonds form S(7) and S(9) ring motifs. In the crystal, molecules are linked by pairs of C—H⋯O hydrogen bonds, forming inversion dimers with R (2) (2)(16) loops. |
format | Online Article Text |
id | pubmed-4158511 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-41585112014-09-23 Isopropyl 1-benzoyl-4-benzoyloxy-2,6-diphenyl-1,2,3,6-tetrahydropyridine-3-carboxylate Govindan, E. Murugavel, K. Amirthaganesan, S. SubbiahPandi, A. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(35)H(31)NO(5), the piperidine ring has an envelope conformation, with the phenyl-substituted C atom adjacent to the methylene C atom as the flap. This flap atom deviates by 0.633 (2) Å from the mean plane of the other five essentially coplanar atoms in the ring (r.m.s. deviation = 0.044 Å). Intramolecular C—H⋯O hydrogen bonds form S(7) and S(9) ring motifs. In the crystal, molecules are linked by pairs of C—H⋯O hydrogen bonds, forming inversion dimers with R (2) (2)(16) loops. International Union of Crystallography 2014-07-05 /pmc/articles/PMC4158511/ /pubmed/25249905 http://dx.doi.org/10.1107/S1600536814015244 Text en © Govindan et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Govindan, E. Murugavel, K. Amirthaganesan, S. SubbiahPandi, A. Isopropyl 1-benzoyl-4-benzoyloxy-2,6-diphenyl-1,2,3,6-tetrahydropyridine-3-carboxylate |
title | Isopropyl 1-benzoyl-4-benzoyloxy-2,6-diphenyl-1,2,3,6-tetrahydropyridine-3-carboxylate |
title_full | Isopropyl 1-benzoyl-4-benzoyloxy-2,6-diphenyl-1,2,3,6-tetrahydropyridine-3-carboxylate |
title_fullStr | Isopropyl 1-benzoyl-4-benzoyloxy-2,6-diphenyl-1,2,3,6-tetrahydropyridine-3-carboxylate |
title_full_unstemmed | Isopropyl 1-benzoyl-4-benzoyloxy-2,6-diphenyl-1,2,3,6-tetrahydropyridine-3-carboxylate |
title_short | Isopropyl 1-benzoyl-4-benzoyloxy-2,6-diphenyl-1,2,3,6-tetrahydropyridine-3-carboxylate |
title_sort | isopropyl 1-benzoyl-4-benzoyloxy-2,6-diphenyl-1,2,3,6-tetrahydropyridine-3-carboxylate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4158511/ https://www.ncbi.nlm.nih.gov/pubmed/25249905 http://dx.doi.org/10.1107/S1600536814015244 |
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