Crystal structure of a layered coordination polymer based on a 4(4) net containing Cd(2+) ions and 1,5-bis­(pyridin-4-yl)pentane linkers

The title compound, poly[[di­aqua­bis­[1,5-bis­(pyridin-4-yl)pentane-κ(2) N:N′]cadmium] bis­(perchlorate) 1,5-bis­(pyridin-4-yl)pentane ethanol mono­solvate], [Cd(C(15)H(18)N(2))(2)(H(2)O)(2)](ClO(4))(2)·C(15)H(18)N(2)·C(2)H(6)O, is a layered coordination polymer built up from highly squashed 4(4) n...

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Detalles Bibliográficos
Autores principales: Harrison, William T. A., Plater, M. John, deSilva, Ben M. deSilva, Foreman, Mark R. St J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4158512/
https://www.ncbi.nlm.nih.gov/pubmed/25249860
http://dx.doi.org/10.1107/S1600536814014779
Descripción
Sumario:The title compound, poly[[di­aqua­bis­[1,5-bis­(pyridin-4-yl)pentane-κ(2) N:N′]cadmium] bis­(perchlorate) 1,5-bis­(pyridin-4-yl)pentane ethanol mono­solvate], [Cd(C(15)H(18)N(2))(2)(H(2)O)(2)](ClO(4))(2)·C(15)H(18)N(2)·C(2)H(6)O, is a layered coordination polymer built up from highly squashed 4(4) nets in which the octa­hedral trans-CdO(2)N(4) nodes (Cd site symmetry -1) are linked by the bifunctional ligands, forming infinite (110) sheets. The cationic sheets are charge-balanced by inter­layer perchlorate ions. A free 1,5-bis­(pyridin-4-yl)pentane mol­ecule and an ethanol mol­ecule of crystallization are also found in the inter­sheet region. A number of O—H⋯O, O—H⋯N and C—H⋯O hydrogen bonds help to consolidate the layered structure.

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