Crystal structure of a layered coordination polymer based on a 4(4) net containing Cd(2+) ions and 1,5-bis­(pyridin-4-yl)pentane linkers

The title compound, poly[[di­aqua­bis­[1,5-bis­(pyridin-4-yl)pentane-κ(2) N:N′]cadmium] bis­(perchlorate) 1,5-bis­(pyridin-4-yl)pentane ethanol mono­solvate], [Cd(C(15)H(18)N(2))(2)(H(2)O)(2)](ClO(4))(2)·C(15)H(18)N(2)·C(2)H(6)O, is a layered coordination polymer built up from highly squashed 4(4) n...

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Autores principales: Harrison, William T. A., Plater, M. John, deSilva, Ben M. deSilva, Foreman, Mark R. St J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4158512/
https://www.ncbi.nlm.nih.gov/pubmed/25249860
http://dx.doi.org/10.1107/S1600536814014779
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author Harrison, William T. A.
Plater, M. John
deSilva, Ben M. deSilva
Foreman, Mark R. St J.
author_facet Harrison, William T. A.
Plater, M. John
deSilva, Ben M. deSilva
Foreman, Mark R. St J.
author_sort Harrison, William T. A.
collection PubMed
description The title compound, poly[[di­aqua­bis­[1,5-bis­(pyridin-4-yl)pentane-κ(2) N:N′]cadmium] bis­(perchlorate) 1,5-bis­(pyridin-4-yl)pentane ethanol mono­solvate], [Cd(C(15)H(18)N(2))(2)(H(2)O)(2)](ClO(4))(2)·C(15)H(18)N(2)·C(2)H(6)O, is a layered coordination polymer built up from highly squashed 4(4) nets in which the octa­hedral trans-CdO(2)N(4) nodes (Cd site symmetry -1) are linked by the bifunctional ligands, forming infinite (110) sheets. The cationic sheets are charge-balanced by inter­layer perchlorate ions. A free 1,5-bis­(pyridin-4-yl)pentane mol­ecule and an ethanol mol­ecule of crystallization are also found in the inter­sheet region. A number of O—H⋯O, O—H⋯N and C—H⋯O hydrogen bonds help to consolidate the layered structure.
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spelling pubmed-41585122014-09-23 Crystal structure of a layered coordination polymer based on a 4(4) net containing Cd(2+) ions and 1,5-bis­(pyridin-4-yl)pentane linkers Harrison, William T. A. Plater, M. John deSilva, Ben M. deSilva Foreman, Mark R. St J. Acta Crystallogr Sect E Struct Rep Online Research Communications The title compound, poly[[di­aqua­bis­[1,5-bis­(pyridin-4-yl)pentane-κ(2) N:N′]cadmium] bis­(perchlorate) 1,5-bis­(pyridin-4-yl)pentane ethanol mono­solvate], [Cd(C(15)H(18)N(2))(2)(H(2)O)(2)](ClO(4))(2)·C(15)H(18)N(2)·C(2)H(6)O, is a layered coordination polymer built up from highly squashed 4(4) nets in which the octa­hedral trans-CdO(2)N(4) nodes (Cd site symmetry -1) are linked by the bifunctional ligands, forming infinite (110) sheets. The cationic sheets are charge-balanced by inter­layer perchlorate ions. A free 1,5-bis­(pyridin-4-yl)pentane mol­ecule and an ethanol mol­ecule of crystallization are also found in the inter­sheet region. A number of O—H⋯O, O—H⋯N and C—H⋯O hydrogen bonds help to consolidate the layered structure. International Union of Crystallography 2014-07-19 /pmc/articles/PMC4158512/ /pubmed/25249860 http://dx.doi.org/10.1107/S1600536814014779 Text en © Harrison et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Harrison, William T. A.
Plater, M. John
deSilva, Ben M. deSilva
Foreman, Mark R. St J.
Crystal structure of a layered coordination polymer based on a 4(4) net containing Cd(2+) ions and 1,5-bis­(pyridin-4-yl)pentane linkers
title Crystal structure of a layered coordination polymer based on a 4(4) net containing Cd(2+) ions and 1,5-bis­(pyridin-4-yl)pentane linkers
title_full Crystal structure of a layered coordination polymer based on a 4(4) net containing Cd(2+) ions and 1,5-bis­(pyridin-4-yl)pentane linkers
title_fullStr Crystal structure of a layered coordination polymer based on a 4(4) net containing Cd(2+) ions and 1,5-bis­(pyridin-4-yl)pentane linkers
title_full_unstemmed Crystal structure of a layered coordination polymer based on a 4(4) net containing Cd(2+) ions and 1,5-bis­(pyridin-4-yl)pentane linkers
title_short Crystal structure of a layered coordination polymer based on a 4(4) net containing Cd(2+) ions and 1,5-bis­(pyridin-4-yl)pentane linkers
title_sort crystal structure of a layered coordination polymer based on a 4(4) net containing cd(2+) ions and 1,5-bis­(pyridin-4-yl)pentane linkers
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4158512/
https://www.ncbi.nlm.nih.gov/pubmed/25249860
http://dx.doi.org/10.1107/S1600536814014779
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