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(E)-3-(9-Hexyl-9H-carbazol-3-yl)acrylic acid

In the title compound, C(21)H(23)NO(2), the hexyl group adopts an extended conformation, the six C atoms are nearly coplanar [maximum deviation = 0.082 (3) Å] and their mean plane is approximately perpendicular to the carbazole ring system, with a dihedral angle of 78.91 (15)°. In the crystal, mol­e...

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Detalles Bibliográficos
Autores principales: Sun, Wan, Liu, Wen-Mo, Li, Sheng-Li
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4158515/
https://www.ncbi.nlm.nih.gov/pubmed/25249926
http://dx.doi.org/10.1107/S1600536814016237
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author Sun, Wan
Liu, Wen-Mo
Li, Sheng-Li
author_facet Sun, Wan
Liu, Wen-Mo
Li, Sheng-Li
author_sort Sun, Wan
collection PubMed
description In the title compound, C(21)H(23)NO(2), the hexyl group adopts an extended conformation, the six C atoms are nearly coplanar [maximum deviation = 0.082 (3) Å] and their mean plane is approximately perpendicular to the carbazole ring system, with a dihedral angle of 78.91 (15)°. In the crystal, mol­ecules are linked by O—H⋯O hydrogen bonds, forming inversion dimers; π–π stacking between carbazole ring systems of adjacent dimers further links the dimers into supra­molecular chains propagating along the b-axis direction [centroid-to-centroid distances = 3.868 (2) and 3.929 (2) Å].
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spelling pubmed-41585152014-09-23 (E)-3-(9-Hexyl-9H-carbazol-3-yl)acrylic acid Sun, Wan Liu, Wen-Mo Li, Sheng-Li Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(21)H(23)NO(2), the hexyl group adopts an extended conformation, the six C atoms are nearly coplanar [maximum deviation = 0.082 (3) Å] and their mean plane is approximately perpendicular to the carbazole ring system, with a dihedral angle of 78.91 (15)°. In the crystal, mol­ecules are linked by O—H⋯O hydrogen bonds, forming inversion dimers; π–π stacking between carbazole ring systems of adjacent dimers further links the dimers into supra­molecular chains propagating along the b-axis direction [centroid-to-centroid distances = 3.868 (2) and 3.929 (2) Å]. International Union of Crystallography 2014-07-31 /pmc/articles/PMC4158515/ /pubmed/25249926 http://dx.doi.org/10.1107/S1600536814016237 Text en © Sun et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Sun, Wan
Liu, Wen-Mo
Li, Sheng-Li
(E)-3-(9-Hexyl-9H-carbazol-3-yl)acrylic acid
title (E)-3-(9-Hexyl-9H-carbazol-3-yl)acrylic acid
title_full (E)-3-(9-Hexyl-9H-carbazol-3-yl)acrylic acid
title_fullStr (E)-3-(9-Hexyl-9H-carbazol-3-yl)acrylic acid
title_full_unstemmed (E)-3-(9-Hexyl-9H-carbazol-3-yl)acrylic acid
title_short (E)-3-(9-Hexyl-9H-carbazol-3-yl)acrylic acid
title_sort (e)-3-(9-hexyl-9h-carbazol-3-yl)acrylic acid
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4158515/
https://www.ncbi.nlm.nih.gov/pubmed/25249926
http://dx.doi.org/10.1107/S1600536814016237
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