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(E)-3-(9-Hexyl-9H-carbazol-3-yl)acrylic acid
In the title compound, C(21)H(23)NO(2), the hexyl group adopts an extended conformation, the six C atoms are nearly coplanar [maximum deviation = 0.082 (3) Å] and their mean plane is approximately perpendicular to the carbazole ring system, with a dihedral angle of 78.91 (15)°. In the crystal, mole...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4158515/ https://www.ncbi.nlm.nih.gov/pubmed/25249926 http://dx.doi.org/10.1107/S1600536814016237 |
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author | Sun, Wan Liu, Wen-Mo Li, Sheng-Li |
author_facet | Sun, Wan Liu, Wen-Mo Li, Sheng-Li |
author_sort | Sun, Wan |
collection | PubMed |
description | In the title compound, C(21)H(23)NO(2), the hexyl group adopts an extended conformation, the six C atoms are nearly coplanar [maximum deviation = 0.082 (3) Å] and their mean plane is approximately perpendicular to the carbazole ring system, with a dihedral angle of 78.91 (15)°. In the crystal, molecules are linked by O—H⋯O hydrogen bonds, forming inversion dimers; π–π stacking between carbazole ring systems of adjacent dimers further links the dimers into supramolecular chains propagating along the b-axis direction [centroid-to-centroid distances = 3.868 (2) and 3.929 (2) Å]. |
format | Online Article Text |
id | pubmed-4158515 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-41585152014-09-23 (E)-3-(9-Hexyl-9H-carbazol-3-yl)acrylic acid Sun, Wan Liu, Wen-Mo Li, Sheng-Li Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(21)H(23)NO(2), the hexyl group adopts an extended conformation, the six C atoms are nearly coplanar [maximum deviation = 0.082 (3) Å] and their mean plane is approximately perpendicular to the carbazole ring system, with a dihedral angle of 78.91 (15)°. In the crystal, molecules are linked by O—H⋯O hydrogen bonds, forming inversion dimers; π–π stacking between carbazole ring systems of adjacent dimers further links the dimers into supramolecular chains propagating along the b-axis direction [centroid-to-centroid distances = 3.868 (2) and 3.929 (2) Å]. International Union of Crystallography 2014-07-31 /pmc/articles/PMC4158515/ /pubmed/25249926 http://dx.doi.org/10.1107/S1600536814016237 Text en © Sun et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Sun, Wan Liu, Wen-Mo Li, Sheng-Li (E)-3-(9-Hexyl-9H-carbazol-3-yl)acrylic acid |
title | (E)-3-(9-Hexyl-9H-carbazol-3-yl)acrylic acid |
title_full | (E)-3-(9-Hexyl-9H-carbazol-3-yl)acrylic acid |
title_fullStr | (E)-3-(9-Hexyl-9H-carbazol-3-yl)acrylic acid |
title_full_unstemmed | (E)-3-(9-Hexyl-9H-carbazol-3-yl)acrylic acid |
title_short | (E)-3-(9-Hexyl-9H-carbazol-3-yl)acrylic acid |
title_sort | (e)-3-(9-hexyl-9h-carbazol-3-yl)acrylic acid |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4158515/ https://www.ncbi.nlm.nih.gov/pubmed/25249926 http://dx.doi.org/10.1107/S1600536814016237 |
work_keys_str_mv | AT sunwan e39hexyl9hcarbazol3ylacrylicacid AT liuwenmo e39hexyl9hcarbazol3ylacrylicacid AT lishengli e39hexyl9hcarbazol3ylacrylicacid |