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Dichlorido{(2E)-2-[phen­yl(pyridin-2-yl)methyl­idene]hydrazinecarbo­thio­amide}cadmium(II) methanol monosolvate

In the title compound, [CdCl(2)(C(13)H(12)N(4)S)]·CH(3)OH, the coord­ination geometry of the Cd(II) ion is slightly distorted square-pyramidal, as indicated by the τ index of 0.36 (8). The S atom, two N atoms from the pyridyl-azomethine moiety and one of the Cl atoms comprise the basal plane, while...

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Detalles Bibliográficos
Autores principales: Aravindakshan, Ambili A., Seena, V., Sithambaresan, M., Kurup, M. R. Prathapachandra
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4158520/
https://www.ncbi.nlm.nih.gov/pubmed/25249883
http://dx.doi.org/10.1107/S1600536814015694
Descripción
Sumario:In the title compound, [CdCl(2)(C(13)H(12)N(4)S)]·CH(3)OH, the coord­ination geometry of the Cd(II) ion is slightly distorted square-pyramidal, as indicated by the τ index of 0.36 (8). The S atom, two N atoms from the pyridyl-azomethine moiety and one of the Cl atoms comprise the basal plane, while the other Cl atom occupies the apical position. The hydrazinecarbo­thio­amide moiety adopts an E conformation with respect to the azomethine bond. The solvate mol­ecule in the crystal lattice plays a major role in inter­connecting adjacent mol­ecules by means of O—H⋯Cl and N—H⋯O hydrogen-bonding inter­actions. A supra­molecular three-dimensional architecture is sustained in terms of further N—H⋯Cl and C—H⋯Cl hydrogen-bonding inter­actions.