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Dichlorido{(2E)-2-[phenyl(pyridin-2-yl)methylidene]hydrazinecarbothioamide}cadmium(II) methanol monosolvate
In the title compound, [CdCl(2)(C(13)H(12)N(4)S)]·CH(3)OH, the coordination geometry of the Cd(II) ion is slightly distorted square-pyramidal, as indicated by the τ index of 0.36 (8). The S atom, two N atoms from the pyridyl-azomethine moiety and one of the Cl atoms comprise the basal plane, while...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4158520/ https://www.ncbi.nlm.nih.gov/pubmed/25249883 http://dx.doi.org/10.1107/S1600536814015694 |
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author | Aravindakshan, Ambili A. Seena, V. Sithambaresan, M. Kurup, M. R. Prathapachandra |
author_facet | Aravindakshan, Ambili A. Seena, V. Sithambaresan, M. Kurup, M. R. Prathapachandra |
author_sort | Aravindakshan, Ambili A. |
collection | PubMed |
description | In the title compound, [CdCl(2)(C(13)H(12)N(4)S)]·CH(3)OH, the coordination geometry of the Cd(II) ion is slightly distorted square-pyramidal, as indicated by the τ index of 0.36 (8). The S atom, two N atoms from the pyridyl-azomethine moiety and one of the Cl atoms comprise the basal plane, while the other Cl atom occupies the apical position. The hydrazinecarbothioamide moiety adopts an E conformation with respect to the azomethine bond. The solvate molecule in the crystal lattice plays a major role in interconnecting adjacent molecules by means of O—H⋯Cl and N—H⋯O hydrogen-bonding interactions. A supramolecular three-dimensional architecture is sustained in terms of further N—H⋯Cl and C—H⋯Cl hydrogen-bonding interactions. |
format | Online Article Text |
id | pubmed-4158520 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-41585202014-09-23 Dichlorido{(2E)-2-[phenyl(pyridin-2-yl)methylidene]hydrazinecarbothioamide}cadmium(II) methanol monosolvate Aravindakshan, Ambili A. Seena, V. Sithambaresan, M. Kurup, M. R. Prathapachandra Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [CdCl(2)(C(13)H(12)N(4)S)]·CH(3)OH, the coordination geometry of the Cd(II) ion is slightly distorted square-pyramidal, as indicated by the τ index of 0.36 (8). The S atom, two N atoms from the pyridyl-azomethine moiety and one of the Cl atoms comprise the basal plane, while the other Cl atom occupies the apical position. The hydrazinecarbothioamide moiety adopts an E conformation with respect to the azomethine bond. The solvate molecule in the crystal lattice plays a major role in interconnecting adjacent molecules by means of O—H⋯Cl and N—H⋯O hydrogen-bonding interactions. A supramolecular three-dimensional architecture is sustained in terms of further N—H⋯Cl and C—H⋯Cl hydrogen-bonding interactions. International Union of Crystallography 2014-07-17 /pmc/articles/PMC4158520/ /pubmed/25249883 http://dx.doi.org/10.1107/S1600536814015694 Text en © Aravindakshan et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Aravindakshan, Ambili A. Seena, V. Sithambaresan, M. Kurup, M. R. Prathapachandra Dichlorido{(2E)-2-[phenyl(pyridin-2-yl)methylidene]hydrazinecarbothioamide}cadmium(II) methanol monosolvate |
title | Dichlorido{(2E)-2-[phenyl(pyridin-2-yl)methylidene]hydrazinecarbothioamide}cadmium(II) methanol monosolvate |
title_full | Dichlorido{(2E)-2-[phenyl(pyridin-2-yl)methylidene]hydrazinecarbothioamide}cadmium(II) methanol monosolvate |
title_fullStr | Dichlorido{(2E)-2-[phenyl(pyridin-2-yl)methylidene]hydrazinecarbothioamide}cadmium(II) methanol monosolvate |
title_full_unstemmed | Dichlorido{(2E)-2-[phenyl(pyridin-2-yl)methylidene]hydrazinecarbothioamide}cadmium(II) methanol monosolvate |
title_short | Dichlorido{(2E)-2-[phenyl(pyridin-2-yl)methylidene]hydrazinecarbothioamide}cadmium(II) methanol monosolvate |
title_sort | dichlorido{(2e)-2-[phenyl(pyridin-2-yl)methylidene]hydrazinecarbothioamide}cadmium(ii) methanol monosolvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4158520/ https://www.ncbi.nlm.nih.gov/pubmed/25249883 http://dx.doi.org/10.1107/S1600536814015694 |
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