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Dichlorido{(2E)-2-[phen­yl(pyridin-2-yl)methyl­idene]hydrazinecarbo­thio­amide}cadmium(II) methanol monosolvate

In the title compound, [CdCl(2)(C(13)H(12)N(4)S)]·CH(3)OH, the coord­ination geometry of the Cd(II) ion is slightly distorted square-pyramidal, as indicated by the τ index of 0.36 (8). The S atom, two N atoms from the pyridyl-azomethine moiety and one of the Cl atoms comprise the basal plane, while...

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Autores principales: Aravindakshan, Ambili A., Seena, V., Sithambaresan, M., Kurup, M. R. Prathapachandra
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4158520/
https://www.ncbi.nlm.nih.gov/pubmed/25249883
http://dx.doi.org/10.1107/S1600536814015694
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author Aravindakshan, Ambili A.
Seena, V.
Sithambaresan, M.
Kurup, M. R. Prathapachandra
author_facet Aravindakshan, Ambili A.
Seena, V.
Sithambaresan, M.
Kurup, M. R. Prathapachandra
author_sort Aravindakshan, Ambili A.
collection PubMed
description In the title compound, [CdCl(2)(C(13)H(12)N(4)S)]·CH(3)OH, the coord­ination geometry of the Cd(II) ion is slightly distorted square-pyramidal, as indicated by the τ index of 0.36 (8). The S atom, two N atoms from the pyridyl-azomethine moiety and one of the Cl atoms comprise the basal plane, while the other Cl atom occupies the apical position. The hydrazinecarbo­thio­amide moiety adopts an E conformation with respect to the azomethine bond. The solvate mol­ecule in the crystal lattice plays a major role in inter­connecting adjacent mol­ecules by means of O—H⋯Cl and N—H⋯O hydrogen-bonding inter­actions. A supra­molecular three-dimensional architecture is sustained in terms of further N—H⋯Cl and C—H⋯Cl hydrogen-bonding inter­actions.
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spelling pubmed-41585202014-09-23 Dichlorido{(2E)-2-[phen­yl(pyridin-2-yl)methyl­idene]hydrazinecarbo­thio­amide}cadmium(II) methanol monosolvate Aravindakshan, Ambili A. Seena, V. Sithambaresan, M. Kurup, M. R. Prathapachandra Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [CdCl(2)(C(13)H(12)N(4)S)]·CH(3)OH, the coord­ination geometry of the Cd(II) ion is slightly distorted square-pyramidal, as indicated by the τ index of 0.36 (8). The S atom, two N atoms from the pyridyl-azomethine moiety and one of the Cl atoms comprise the basal plane, while the other Cl atom occupies the apical position. The hydrazinecarbo­thio­amide moiety adopts an E conformation with respect to the azomethine bond. The solvate mol­ecule in the crystal lattice plays a major role in inter­connecting adjacent mol­ecules by means of O—H⋯Cl and N—H⋯O hydrogen-bonding inter­actions. A supra­molecular three-dimensional architecture is sustained in terms of further N—H⋯Cl and C—H⋯Cl hydrogen-bonding inter­actions. International Union of Crystallography 2014-07-17 /pmc/articles/PMC4158520/ /pubmed/25249883 http://dx.doi.org/10.1107/S1600536814015694 Text en © Aravindakshan et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Aravindakshan, Ambili A.
Seena, V.
Sithambaresan, M.
Kurup, M. R. Prathapachandra
Dichlorido{(2E)-2-[phen­yl(pyridin-2-yl)methyl­idene]hydrazinecarbo­thio­amide}cadmium(II) methanol monosolvate
title Dichlorido{(2E)-2-[phen­yl(pyridin-2-yl)methyl­idene]hydrazinecarbo­thio­amide}cadmium(II) methanol monosolvate
title_full Dichlorido{(2E)-2-[phen­yl(pyridin-2-yl)methyl­idene]hydrazinecarbo­thio­amide}cadmium(II) methanol monosolvate
title_fullStr Dichlorido{(2E)-2-[phen­yl(pyridin-2-yl)methyl­idene]hydrazinecarbo­thio­amide}cadmium(II) methanol monosolvate
title_full_unstemmed Dichlorido{(2E)-2-[phen­yl(pyridin-2-yl)methyl­idene]hydrazinecarbo­thio­amide}cadmium(II) methanol monosolvate
title_short Dichlorido{(2E)-2-[phen­yl(pyridin-2-yl)methyl­idene]hydrazinecarbo­thio­amide}cadmium(II) methanol monosolvate
title_sort dichlorido{(2e)-2-[phen­yl(pyridin-2-yl)methyl­idene]hydrazinecarbo­thio­amide}cadmium(ii) methanol monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4158520/
https://www.ncbi.nlm.nih.gov/pubmed/25249883
http://dx.doi.org/10.1107/S1600536814015694
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