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Bis(2-amino-4-phenyl-1,3-thiazol-3-ium) tetrachloridopalladate(II)
The title compound, (C(9)H(9)N(2)S)(2)[PdCl(4)], consists of two monoprotonated 2-amino-4-phenyl-1,3-thiazole molecules and one tetrachloridopalladate anion. The organic molecules exhibit a dihedral angle between the main rings planes of 31.82 (9)°. In the anion, the Pd(II) atom is located on a c...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2014
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4158524/ https://www.ncbi.nlm.nih.gov/pubmed/25249879 http://dx.doi.org/10.1107/S1600536814015360 |
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| author | Reyes-Martínez, Reyna Carballo, Rubén M. Mena-Rejón, Gonzalo J. Hernández-Ortega, Simón Cáceres-Castillo, David |
| author_facet | Reyes-Martínez, Reyna Carballo, Rubén M. Mena-Rejón, Gonzalo J. Hernández-Ortega, Simón Cáceres-Castillo, David |
| author_sort | Reyes-Martínez, Reyna |
| collection | PubMed |
| description | The title compound, (C(9)H(9)N(2)S)(2)[PdCl(4)], consists of two monoprotonated 2-amino-4-phenyl-1,3-thiazole molecules and one tetrachloridopalladate anion. The organic molecules exhibit a dihedral angle between the main rings planes of 31.82 (9)°. In the anion, the Pd(II) atom is located on a crystallographic centre of symmetry with a square-planar geometry. In the crystal, the anions and cations are connected through bifurcated N—H⋯Cl hydrogen bonds, and these interactions lead to hydrogen-bonded tapes of cations and anions along [100]. |
| format | Online Article Text |
| id | pubmed-4158524 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2014 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-41585242014-09-23 Bis(2-amino-4-phenyl-1,3-thiazol-3-ium) tetrachloridopalladate(II) Reyes-Martínez, Reyna Carballo, Rubén M. Mena-Rejón, Gonzalo J. Hernández-Ortega, Simón Cáceres-Castillo, David Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, (C(9)H(9)N(2)S)(2)[PdCl(4)], consists of two monoprotonated 2-amino-4-phenyl-1,3-thiazole molecules and one tetrachloridopalladate anion. The organic molecules exhibit a dihedral angle between the main rings planes of 31.82 (9)°. In the anion, the Pd(II) atom is located on a crystallographic centre of symmetry with a square-planar geometry. In the crystal, the anions and cations are connected through bifurcated N—H⋯Cl hydrogen bonds, and these interactions lead to hydrogen-bonded tapes of cations and anions along [100]. International Union of Crystallography 2014-07-11 /pmc/articles/PMC4158524/ /pubmed/25249879 http://dx.doi.org/10.1107/S1600536814015360 Text en © Reyes-Martínez et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Reyes-Martínez, Reyna Carballo, Rubén M. Mena-Rejón, Gonzalo J. Hernández-Ortega, Simón Cáceres-Castillo, David Bis(2-amino-4-phenyl-1,3-thiazol-3-ium) tetrachloridopalladate(II) |
| title | Bis(2-amino-4-phenyl-1,3-thiazol-3-ium) tetrachloridopalladate(II) |
| title_full | Bis(2-amino-4-phenyl-1,3-thiazol-3-ium) tetrachloridopalladate(II) |
| title_fullStr | Bis(2-amino-4-phenyl-1,3-thiazol-3-ium) tetrachloridopalladate(II) |
| title_full_unstemmed | Bis(2-amino-4-phenyl-1,3-thiazol-3-ium) tetrachloridopalladate(II) |
| title_short | Bis(2-amino-4-phenyl-1,3-thiazol-3-ium) tetrachloridopalladate(II) |
| title_sort | bis(2-amino-4-phenyl-1,3-thiazol-3-ium) tetrachloridopalladate(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4158524/ https://www.ncbi.nlm.nih.gov/pubmed/25249879 http://dx.doi.org/10.1107/S1600536814015360 |
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