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Bis{2-methoxy-6-[(E)-(4-methylbenzyl)iminomethyl]phenolato}palladium(II) chloroform monosolvate
In the title complex, [Pd(C(16)H(16)NO(2))(2)]·CHCl(3), the Pd(II) cation lies on an inversion center. One Cl atom of the CHCl(3) solvent molecule lies on a twofold axis and the C—H group is disordered with equal occupancies about this axis with the other Cl atom in a general position with full occ...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4158526/ https://www.ncbi.nlm.nih.gov/pubmed/25249876 http://dx.doi.org/10.1107/S1600536814015025 |
Sumario: | In the title complex, [Pd(C(16)H(16)NO(2))(2)]·CHCl(3), the Pd(II) cation lies on an inversion center. One Cl atom of the CHCl(3) solvent molecule lies on a twofold axis and the C—H group is disordered with equal occupancies about this axis with the other Cl atom in a general position with full occupancy. The Pd(II) cation is four-coordinate and adopts a square-planar geometry via coordination of the imine N and phenolic O atoms of the two bidentate Schiff base anions. The N and O atoms of these ligands are mutually trans. The plane of the benzene ring makes a dihedral angle of 73.52 (10)° with that of the methoxyphenolate ring. In the crystal, molecules of the Pd(II) complex are arranged into sheets parallel to the ac plane, and the chloroform solvent molecules are located in the interstitial areas between the complex molecules. Weak intermolecular C—H⋯O and C—H⋯π interactions stabilize the packing. |
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