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Bis{2-methoxy-6-[(E)-(4-methylbenzyl)iminomethyl]phenolato}palladium(II) chloroform monosolvate
In the title complex, [Pd(C(16)H(16)NO(2))(2)]·CHCl(3), the Pd(II) cation lies on an inversion center. One Cl atom of the CHCl(3) solvent molecule lies on a twofold axis and the C—H group is disordered with equal occupancies about this axis with the other Cl atom in a general position with full occ...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4158526/ https://www.ncbi.nlm.nih.gov/pubmed/25249876 http://dx.doi.org/10.1107/S1600536814015025 |
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author | Bahron, Hadariah Tajuddin, Amalina Mohd Ibrahim, Wan Nazihah Wan Chantrapromma, Suchada Fun, Hoong-Kun |
author_facet | Bahron, Hadariah Tajuddin, Amalina Mohd Ibrahim, Wan Nazihah Wan Chantrapromma, Suchada Fun, Hoong-Kun |
author_sort | Bahron, Hadariah |
collection | PubMed |
description | In the title complex, [Pd(C(16)H(16)NO(2))(2)]·CHCl(3), the Pd(II) cation lies on an inversion center. One Cl atom of the CHCl(3) solvent molecule lies on a twofold axis and the C—H group is disordered with equal occupancies about this axis with the other Cl atom in a general position with full occupancy. The Pd(II) cation is four-coordinate and adopts a square-planar geometry via coordination of the imine N and phenolic O atoms of the two bidentate Schiff base anions. The N and O atoms of these ligands are mutually trans. The plane of the benzene ring makes a dihedral angle of 73.52 (10)° with that of the methoxyphenolate ring. In the crystal, molecules of the Pd(II) complex are arranged into sheets parallel to the ac plane, and the chloroform solvent molecules are located in the interstitial areas between the complex molecules. Weak intermolecular C—H⋯O and C—H⋯π interactions stabilize the packing. |
format | Online Article Text |
id | pubmed-4158526 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-41585262014-09-23 Bis{2-methoxy-6-[(E)-(4-methylbenzyl)iminomethyl]phenolato}palladium(II) chloroform monosolvate Bahron, Hadariah Tajuddin, Amalina Mohd Ibrahim, Wan Nazihah Wan Chantrapromma, Suchada Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Pd(C(16)H(16)NO(2))(2)]·CHCl(3), the Pd(II) cation lies on an inversion center. One Cl atom of the CHCl(3) solvent molecule lies on a twofold axis and the C—H group is disordered with equal occupancies about this axis with the other Cl atom in a general position with full occupancy. The Pd(II) cation is four-coordinate and adopts a square-planar geometry via coordination of the imine N and phenolic O atoms of the two bidentate Schiff base anions. The N and O atoms of these ligands are mutually trans. The plane of the benzene ring makes a dihedral angle of 73.52 (10)° with that of the methoxyphenolate ring. In the crystal, molecules of the Pd(II) complex are arranged into sheets parallel to the ac plane, and the chloroform solvent molecules are located in the interstitial areas between the complex molecules. Weak intermolecular C—H⋯O and C—H⋯π interactions stabilize the packing. International Union of Crystallography 2014-07-02 /pmc/articles/PMC4158526/ /pubmed/25249876 http://dx.doi.org/10.1107/S1600536814015025 Text en © Bahron et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Bahron, Hadariah Tajuddin, Amalina Mohd Ibrahim, Wan Nazihah Wan Chantrapromma, Suchada Fun, Hoong-Kun Bis{2-methoxy-6-[(E)-(4-methylbenzyl)iminomethyl]phenolato}palladium(II) chloroform monosolvate |
title | Bis{2-methoxy-6-[(E)-(4-methylbenzyl)iminomethyl]phenolato}palladium(II) chloroform monosolvate |
title_full | Bis{2-methoxy-6-[(E)-(4-methylbenzyl)iminomethyl]phenolato}palladium(II) chloroform monosolvate |
title_fullStr | Bis{2-methoxy-6-[(E)-(4-methylbenzyl)iminomethyl]phenolato}palladium(II) chloroform monosolvate |
title_full_unstemmed | Bis{2-methoxy-6-[(E)-(4-methylbenzyl)iminomethyl]phenolato}palladium(II) chloroform monosolvate |
title_short | Bis{2-methoxy-6-[(E)-(4-methylbenzyl)iminomethyl]phenolato}palladium(II) chloroform monosolvate |
title_sort | bis{2-methoxy-6-[(e)-(4-methylbenzyl)iminomethyl]phenolato}palladium(ii) chloroform monosolvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4158526/ https://www.ncbi.nlm.nih.gov/pubmed/25249876 http://dx.doi.org/10.1107/S1600536814015025 |
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