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Bis{2-meth­oxy-6-[(E)-(4-methyl­benz­yl)imino­meth­yl]phenolato}palladium(II) chloro­form monosolvate

In the title complex, [Pd(C(16)H(16)NO(2))(2)]·CHCl(3), the Pd(II) cation lies on an inversion center. One Cl atom of the CHCl(3) solvent mol­ecule lies on a twofold axis and the C—H group is disordered with equal occupancies about this axis with the other Cl atom in a general position with full occ...

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Autores principales: Bahron, Hadariah, Tajuddin, Amalina Mohd, Ibrahim, Wan Nazihah Wan, Chantrapromma, Suchada, Fun, Hoong-Kun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4158526/
https://www.ncbi.nlm.nih.gov/pubmed/25249876
http://dx.doi.org/10.1107/S1600536814015025
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author Bahron, Hadariah
Tajuddin, Amalina Mohd
Ibrahim, Wan Nazihah Wan
Chantrapromma, Suchada
Fun, Hoong-Kun
author_facet Bahron, Hadariah
Tajuddin, Amalina Mohd
Ibrahim, Wan Nazihah Wan
Chantrapromma, Suchada
Fun, Hoong-Kun
author_sort Bahron, Hadariah
collection PubMed
description In the title complex, [Pd(C(16)H(16)NO(2))(2)]·CHCl(3), the Pd(II) cation lies on an inversion center. One Cl atom of the CHCl(3) solvent mol­ecule lies on a twofold axis and the C—H group is disordered with equal occupancies about this axis with the other Cl atom in a general position with full occupancy. The Pd(II) cation is four-coordinate and adopts a square-planar geometry via coordination of the imine N and phenolic O atoms of the two bidentate Schiff base anions. The N and O atoms of these ligands are mutually trans. The plane of the benzene ring makes a dihedral angle of 73.52 (10)° with that of the meth­oxy­phenolate ring. In the crystal, mol­ecules of the Pd(II) complex are arranged into sheets parallel to the ac plane, and the chloro­form solvent mol­ecules are located in the inter­stitial areas between the complex mol­ecules. Weak inter­molecular C—H⋯O and C—H⋯π inter­actions stabilize the packing.
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spelling pubmed-41585262014-09-23 Bis{2-meth­oxy-6-[(E)-(4-methyl­benz­yl)imino­meth­yl]phenolato}palladium(II) chloro­form monosolvate Bahron, Hadariah Tajuddin, Amalina Mohd Ibrahim, Wan Nazihah Wan Chantrapromma, Suchada Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Pd(C(16)H(16)NO(2))(2)]·CHCl(3), the Pd(II) cation lies on an inversion center. One Cl atom of the CHCl(3) solvent mol­ecule lies on a twofold axis and the C—H group is disordered with equal occupancies about this axis with the other Cl atom in a general position with full occupancy. The Pd(II) cation is four-coordinate and adopts a square-planar geometry via coordination of the imine N and phenolic O atoms of the two bidentate Schiff base anions. The N and O atoms of these ligands are mutually trans. The plane of the benzene ring makes a dihedral angle of 73.52 (10)° with that of the meth­oxy­phenolate ring. In the crystal, mol­ecules of the Pd(II) complex are arranged into sheets parallel to the ac plane, and the chloro­form solvent mol­ecules are located in the inter­stitial areas between the complex mol­ecules. Weak inter­molecular C—H⋯O and C—H⋯π inter­actions stabilize the packing. International Union of Crystallography 2014-07-02 /pmc/articles/PMC4158526/ /pubmed/25249876 http://dx.doi.org/10.1107/S1600536814015025 Text en © Bahron et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Bahron, Hadariah
Tajuddin, Amalina Mohd
Ibrahim, Wan Nazihah Wan
Chantrapromma, Suchada
Fun, Hoong-Kun
Bis{2-meth­oxy-6-[(E)-(4-methyl­benz­yl)imino­meth­yl]phenolato}palladium(II) chloro­form monosolvate
title Bis{2-meth­oxy-6-[(E)-(4-methyl­benz­yl)imino­meth­yl]phenolato}palladium(II) chloro­form monosolvate
title_full Bis{2-meth­oxy-6-[(E)-(4-methyl­benz­yl)imino­meth­yl]phenolato}palladium(II) chloro­form monosolvate
title_fullStr Bis{2-meth­oxy-6-[(E)-(4-methyl­benz­yl)imino­meth­yl]phenolato}palladium(II) chloro­form monosolvate
title_full_unstemmed Bis{2-meth­oxy-6-[(E)-(4-methyl­benz­yl)imino­meth­yl]phenolato}palladium(II) chloro­form monosolvate
title_short Bis{2-meth­oxy-6-[(E)-(4-methyl­benz­yl)imino­meth­yl]phenolato}palladium(II) chloro­form monosolvate
title_sort bis{2-meth­oxy-6-[(e)-(4-methyl­benz­yl)imino­meth­yl]phenolato}palladium(ii) chloro­form monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4158526/
https://www.ncbi.nlm.nih.gov/pubmed/25249876
http://dx.doi.org/10.1107/S1600536814015025
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