Bis(2-nitro­phen­yl)methane

In the title compound, C(13)H(10)N(2)O(4), the nitro groups are twisted significantly relative to the benzene rings [dihedral angles = 16.64 (18) and 28.02 (11)°]. The benzene groups are nearly perpendicular to each other [dihedral angle = 87.72 (6)°]. Short inter­molecular N⋯O and C⋯O [2.981 (2) an...

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Autores principales: Janzen, Daron E., Crepeau, Laura E., Hageseth, Benjamin D., Wollack, James W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4158535/
https://www.ncbi.nlm.nih.gov/pubmed/25249909
http://dx.doi.org/10.1107/S1600536814015438
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author Janzen, Daron E.
Crepeau, Laura E.
Hageseth, Benjamin D.
Wollack, James W.
author_facet Janzen, Daron E.
Crepeau, Laura E.
Hageseth, Benjamin D.
Wollack, James W.
author_sort Janzen, Daron E.
collection PubMed
description In the title compound, C(13)H(10)N(2)O(4), the nitro groups are twisted significantly relative to the benzene rings [dihedral angles = 16.64 (18) and 28.02 (11)°]. The benzene groups are nearly perpendicular to each other [dihedral angle = 87.72 (6)°]. Short inter­molecular N⋯O and C⋯O [2.981 (2) and 3.060 (2) Å, respectively] contacts suggest possible weak π-inter­actions between nitro groups and between benzene and nitro groups. In addition, there are π–π inter­actions between one benzene group and an inversion-related equivalent [inter­planar separation = 3.494 (2) Å].
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spelling pubmed-41585352014-09-23 Bis(2-nitro­phen­yl)methane Janzen, Daron E. Crepeau, Laura E. Hageseth, Benjamin D. Wollack, James W. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(13)H(10)N(2)O(4), the nitro groups are twisted significantly relative to the benzene rings [dihedral angles = 16.64 (18) and 28.02 (11)°]. The benzene groups are nearly perpendicular to each other [dihedral angle = 87.72 (6)°]. Short inter­molecular N⋯O and C⋯O [2.981 (2) and 3.060 (2) Å, respectively] contacts suggest possible weak π-inter­actions between nitro groups and between benzene and nitro groups. In addition, there are π–π inter­actions between one benzene group and an inversion-related equivalent [inter­planar separation = 3.494 (2) Å]. International Union of Crystallography 2014-07-05 /pmc/articles/PMC4158535/ /pubmed/25249909 http://dx.doi.org/10.1107/S1600536814015438 Text en © Janzen et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Janzen, Daron E.
Crepeau, Laura E.
Hageseth, Benjamin D.
Wollack, James W.
Bis(2-nitro­phen­yl)methane
title Bis(2-nitro­phen­yl)methane
title_full Bis(2-nitro­phen­yl)methane
title_fullStr Bis(2-nitro­phen­yl)methane
title_full_unstemmed Bis(2-nitro­phen­yl)methane
title_short Bis(2-nitro­phen­yl)methane
title_sort bis(2-nitro­phen­yl)methane
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4158535/
https://www.ncbi.nlm.nih.gov/pubmed/25249909
http://dx.doi.org/10.1107/S1600536814015438
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AT crepeaulaurae bis2nitrophenylmethane
AT hagesethbenjamind bis2nitrophenylmethane
AT wollackjamesw bis2nitrophenylmethane

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