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4-Fluoro-N-(4-hy­droxy­benzyl­idene)aniline

In the title compound, C(13)H(10)FNO, the benzene ring planes are inclined at an angle of 50.52 (8)°. A characteristic of aromatic Schiff bases with N-aryl substituents is that the terminal phenyl rings are twisted relative to the plane of the HC=N link between them. In this case, the HC=N unit make...

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Detalles Bibliográficos
Autores principales: Jothi, L., Anuradha, G., Vasuki, G., Babu, R. Ramesh, Ramamurthi, K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4158537/
https://www.ncbi.nlm.nih.gov/pubmed/25249910
http://dx.doi.org/10.1107/S1600536814015153
Descripción
Sumario:In the title compound, C(13)H(10)FNO, the benzene ring planes are inclined at an angle of 50.52 (8)°. A characteristic of aromatic Schiff bases with N-aryl substituents is that the terminal phenyl rings are twisted relative to the plane of the HC=N link between them. In this case, the HC=N unit makes dihedral angles of 10.6 (2) and 40.5 (2)° with the hy­droxy­benzene and fluro­benzene rings, respectively. In the crystal, O—H⋯N and C—H⋯F hydrogen bonds lead to the formation of chains along the c- and b-axis directions, respectively. C—H⋯π contacts link mol­ecules along a and these contacts combine to generate a three-dimensional network with mol­ecules stacked along the b-axis direction.