Cargando…
4-Fluoro-N-(4-hydroxybenzylidene)aniline
In the title compound, C(13)H(10)FNO, the benzene ring planes are inclined at an angle of 50.52 (8)°. A characteristic of aromatic Schiff bases with N-aryl substituents is that the terminal phenyl rings are twisted relative to the plane of the HC=N link between them. In this case, the HC=N unit make...
Autores principales: | , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4158537/ https://www.ncbi.nlm.nih.gov/pubmed/25249910 http://dx.doi.org/10.1107/S1600536814015153 |
Sumario: | In the title compound, C(13)H(10)FNO, the benzene ring planes are inclined at an angle of 50.52 (8)°. A characteristic of aromatic Schiff bases with N-aryl substituents is that the terminal phenyl rings are twisted relative to the plane of the HC=N link between them. In this case, the HC=N unit makes dihedral angles of 10.6 (2) and 40.5 (2)° with the hydroxybenzene and flurobenzene rings, respectively. In the crystal, O—H⋯N and C—H⋯F hydrogen bonds lead to the formation of chains along the c- and b-axis directions, respectively. C—H⋯π contacts link molecules along a and these contacts combine to generate a three-dimensional network with molecules stacked along the b-axis direction. |
---|