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4-Fluoro-N-(4-hydroxybenzylidene)aniline
In the title compound, C(13)H(10)FNO, the benzene ring planes are inclined at an angle of 50.52 (8)°. A characteristic of aromatic Schiff bases with N-aryl substituents is that the terminal phenyl rings are twisted relative to the plane of the HC=N link between them. In this case, the HC=N unit make...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4158537/ https://www.ncbi.nlm.nih.gov/pubmed/25249910 http://dx.doi.org/10.1107/S1600536814015153 |
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author | Jothi, L. Anuradha, G. Vasuki, G. Babu, R. Ramesh Ramamurthi, K. |
author_facet | Jothi, L. Anuradha, G. Vasuki, G. Babu, R. Ramesh Ramamurthi, K. |
author_sort | Jothi, L. |
collection | PubMed |
description | In the title compound, C(13)H(10)FNO, the benzene ring planes are inclined at an angle of 50.52 (8)°. A characteristic of aromatic Schiff bases with N-aryl substituents is that the terminal phenyl rings are twisted relative to the plane of the HC=N link between them. In this case, the HC=N unit makes dihedral angles of 10.6 (2) and 40.5 (2)° with the hydroxybenzene and flurobenzene rings, respectively. In the crystal, O—H⋯N and C—H⋯F hydrogen bonds lead to the formation of chains along the c- and b-axis directions, respectively. C—H⋯π contacts link molecules along a and these contacts combine to generate a three-dimensional network with molecules stacked along the b-axis direction. |
format | Online Article Text |
id | pubmed-4158537 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-41585372014-09-23 4-Fluoro-N-(4-hydroxybenzylidene)aniline Jothi, L. Anuradha, G. Vasuki, G. Babu, R. Ramesh Ramamurthi, K. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(13)H(10)FNO, the benzene ring planes are inclined at an angle of 50.52 (8)°. A characteristic of aromatic Schiff bases with N-aryl substituents is that the terminal phenyl rings are twisted relative to the plane of the HC=N link between them. In this case, the HC=N unit makes dihedral angles of 10.6 (2) and 40.5 (2)° with the hydroxybenzene and flurobenzene rings, respectively. In the crystal, O—H⋯N and C—H⋯F hydrogen bonds lead to the formation of chains along the c- and b-axis directions, respectively. C—H⋯π contacts link molecules along a and these contacts combine to generate a three-dimensional network with molecules stacked along the b-axis direction. International Union of Crystallography 2014-07-11 /pmc/articles/PMC4158537/ /pubmed/25249910 http://dx.doi.org/10.1107/S1600536814015153 Text en © Jothi et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Jothi, L. Anuradha, G. Vasuki, G. Babu, R. Ramesh Ramamurthi, K. 4-Fluoro-N-(4-hydroxybenzylidene)aniline |
title | 4-Fluoro-N-(4-hydroxybenzylidene)aniline |
title_full | 4-Fluoro-N-(4-hydroxybenzylidene)aniline |
title_fullStr | 4-Fluoro-N-(4-hydroxybenzylidene)aniline |
title_full_unstemmed | 4-Fluoro-N-(4-hydroxybenzylidene)aniline |
title_short | 4-Fluoro-N-(4-hydroxybenzylidene)aniline |
title_sort | 4-fluoro-n-(4-hydroxybenzylidene)aniline |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4158537/ https://www.ncbi.nlm.nih.gov/pubmed/25249910 http://dx.doi.org/10.1107/S1600536814015153 |
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