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4-Fluoro-N-(4-hy­droxy­benzyl­idene)aniline

In the title compound, C(13)H(10)FNO, the benzene ring planes are inclined at an angle of 50.52 (8)°. A characteristic of aromatic Schiff bases with N-aryl substituents is that the terminal phenyl rings are twisted relative to the plane of the HC=N link between them. In this case, the HC=N unit make...

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Autores principales: Jothi, L., Anuradha, G., Vasuki, G., Babu, R. Ramesh, Ramamurthi, K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4158537/
https://www.ncbi.nlm.nih.gov/pubmed/25249910
http://dx.doi.org/10.1107/S1600536814015153
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author Jothi, L.
Anuradha, G.
Vasuki, G.
Babu, R. Ramesh
Ramamurthi, K.
author_facet Jothi, L.
Anuradha, G.
Vasuki, G.
Babu, R. Ramesh
Ramamurthi, K.
author_sort Jothi, L.
collection PubMed
description In the title compound, C(13)H(10)FNO, the benzene ring planes are inclined at an angle of 50.52 (8)°. A characteristic of aromatic Schiff bases with N-aryl substituents is that the terminal phenyl rings are twisted relative to the plane of the HC=N link between them. In this case, the HC=N unit makes dihedral angles of 10.6 (2) and 40.5 (2)° with the hy­droxy­benzene and fluro­benzene rings, respectively. In the crystal, O—H⋯N and C—H⋯F hydrogen bonds lead to the formation of chains along the c- and b-axis directions, respectively. C—H⋯π contacts link mol­ecules along a and these contacts combine to generate a three-dimensional network with mol­ecules stacked along the b-axis direction.
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spelling pubmed-41585372014-09-23 4-Fluoro-N-(4-hy­droxy­benzyl­idene)aniline Jothi, L. Anuradha, G. Vasuki, G. Babu, R. Ramesh Ramamurthi, K. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(13)H(10)FNO, the benzene ring planes are inclined at an angle of 50.52 (8)°. A characteristic of aromatic Schiff bases with N-aryl substituents is that the terminal phenyl rings are twisted relative to the plane of the HC=N link between them. In this case, the HC=N unit makes dihedral angles of 10.6 (2) and 40.5 (2)° with the hy­droxy­benzene and fluro­benzene rings, respectively. In the crystal, O—H⋯N and C—H⋯F hydrogen bonds lead to the formation of chains along the c- and b-axis directions, respectively. C—H⋯π contacts link mol­ecules along a and these contacts combine to generate a three-dimensional network with mol­ecules stacked along the b-axis direction. International Union of Crystallography 2014-07-11 /pmc/articles/PMC4158537/ /pubmed/25249910 http://dx.doi.org/10.1107/S1600536814015153 Text en © Jothi et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Jothi, L.
Anuradha, G.
Vasuki, G.
Babu, R. Ramesh
Ramamurthi, K.
4-Fluoro-N-(4-hy­droxy­benzyl­idene)aniline
title 4-Fluoro-N-(4-hy­droxy­benzyl­idene)aniline
title_full 4-Fluoro-N-(4-hy­droxy­benzyl­idene)aniline
title_fullStr 4-Fluoro-N-(4-hy­droxy­benzyl­idene)aniline
title_full_unstemmed 4-Fluoro-N-(4-hy­droxy­benzyl­idene)aniline
title_short 4-Fluoro-N-(4-hy­droxy­benzyl­idene)aniline
title_sort 4-fluoro-n-(4-hy­droxy­benzyl­idene)aniline
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4158537/
https://www.ncbi.nlm.nih.gov/pubmed/25249910
http://dx.doi.org/10.1107/S1600536814015153
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AT ramamurthik 4fluoron4hydroxybenzylideneaniline