3-(2,4-Di­chloro­phen­oxy)-1-(4-meth­oxy­benz­yl)-4-(4-nitro­phen­yl)azetidin-2-one

The β-lactam ring of the title compound, C(23)H(18)Cl(2)N(2)O(5), is nearly planar [maximum deviation = 0.019 (2) Å for the N atom] and its mean plane makes dihedral angles of 56.86 (15), 68.83 (15) and 83.75 (15)° with the di­chloro-, nitro- and meth­oxy-substituted benzene rings, respectively. In...

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Autores principales: Atioğlu, Zeliha, Akkurt, Mehmet, Jarrahpour, Aliasghar, Heiran, Roghayeh, Özdemir, Namık
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4158542/
https://www.ncbi.nlm.nih.gov/pubmed/25249889
http://dx.doi.org/10.1107/S1600536814015013
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author Atioğlu, Zeliha
Akkurt, Mehmet
Jarrahpour, Aliasghar
Heiran, Roghayeh
Özdemir, Namık
author_facet Atioğlu, Zeliha
Akkurt, Mehmet
Jarrahpour, Aliasghar
Heiran, Roghayeh
Özdemir, Namık
author_sort Atioğlu, Zeliha
collection PubMed
description The β-lactam ring of the title compound, C(23)H(18)Cl(2)N(2)O(5), is nearly planar [maximum deviation = 0.019 (2) Å for the N atom] and its mean plane makes dihedral angles of 56.86 (15), 68.83 (15) and 83.75 (15)° with the di­chloro-, nitro- and meth­oxy-substituted benzene rings, respectively. In the crystal, mol­ecules are linked by pairs of C—H⋯O hydrogen bonds, forming inversion dimers with R (2) (2)(10) loops. The dimers are linked by further C—H⋯O hydrogen bonds, forming sheets lying parallel to (001). The mol­ecular packing is further stabilized by C—H⋯π inter­actions.
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spelling pubmed-41585422014-09-23 3-(2,4-Di­chloro­phen­oxy)-1-(4-meth­oxy­benz­yl)-4-(4-nitro­phen­yl)azetidin-2-one Atioğlu, Zeliha Akkurt, Mehmet Jarrahpour, Aliasghar Heiran, Roghayeh Özdemir, Namık Acta Crystallogr Sect E Struct Rep Online Organic Papers The β-lactam ring of the title compound, C(23)H(18)Cl(2)N(2)O(5), is nearly planar [maximum deviation = 0.019 (2) Å for the N atom] and its mean plane makes dihedral angles of 56.86 (15), 68.83 (15) and 83.75 (15)° with the di­chloro-, nitro- and meth­oxy-substituted benzene rings, respectively. In the crystal, mol­ecules are linked by pairs of C—H⋯O hydrogen bonds, forming inversion dimers with R (2) (2)(10) loops. The dimers are linked by further C—H⋯O hydrogen bonds, forming sheets lying parallel to (001). The mol­ecular packing is further stabilized by C—H⋯π inter­actions. International Union of Crystallography 2014-07-02 /pmc/articles/PMC4158542/ /pubmed/25249889 http://dx.doi.org/10.1107/S1600536814015013 Text en © Atioğlu et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Atioğlu, Zeliha
Akkurt, Mehmet
Jarrahpour, Aliasghar
Heiran, Roghayeh
Özdemir, Namık
3-(2,4-Di­chloro­phen­oxy)-1-(4-meth­oxy­benz­yl)-4-(4-nitro­phen­yl)azetidin-2-one
title 3-(2,4-Di­chloro­phen­oxy)-1-(4-meth­oxy­benz­yl)-4-(4-nitro­phen­yl)azetidin-2-one
title_full 3-(2,4-Di­chloro­phen­oxy)-1-(4-meth­oxy­benz­yl)-4-(4-nitro­phen­yl)azetidin-2-one
title_fullStr 3-(2,4-Di­chloro­phen­oxy)-1-(4-meth­oxy­benz­yl)-4-(4-nitro­phen­yl)azetidin-2-one
title_full_unstemmed 3-(2,4-Di­chloro­phen­oxy)-1-(4-meth­oxy­benz­yl)-4-(4-nitro­phen­yl)azetidin-2-one
title_short 3-(2,4-Di­chloro­phen­oxy)-1-(4-meth­oxy­benz­yl)-4-(4-nitro­phen­yl)azetidin-2-one
title_sort 3-(2,4-di­chloro­phen­oxy)-1-(4-meth­oxy­benz­yl)-4-(4-nitro­phen­yl)azetidin-2-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4158542/
https://www.ncbi.nlm.nih.gov/pubmed/25249889
http://dx.doi.org/10.1107/S1600536814015013
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AT heiranroghayeh 324dichlorophenoxy14methoxybenzyl44nitrophenylazetidin2one
AT ozdemirnamık 324dichlorophenoxy14methoxybenzyl44nitrophenylazetidin2one

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