Crystal structure of the high-energy-density material guanylurea dipicryl­amide

The title compound, 1-carbamoylguanidinium bis­(2,4,6-tri­nitro­phen­yl)amide [H(2)NC(=O)NHC(NH(2))(2)](+)[N{C(6)H(2)(NO(2))(3)-2,4,6}(2)](−) (= guanylurea dipicryl­amide), was prepared as dark-red block-like crystals in 70% yield by salt-metathesis reaction between guanylurea sulfate and sodium dip...

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Autores principales: Deblitz, Raik, Hrib, Cristian G., Hilfert, Liane, Edelmann, Frank T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4158545/
https://www.ncbi.nlm.nih.gov/pubmed/25249869
http://dx.doi.org/10.1107/S1600536814017164
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author Deblitz, Raik
Hrib, Cristian G.
Hilfert, Liane
Edelmann, Frank T.
author_facet Deblitz, Raik
Hrib, Cristian G.
Hilfert, Liane
Edelmann, Frank T.
author_sort Deblitz, Raik
collection PubMed
description The title compound, 1-carbamoylguanidinium bis­(2,4,6-tri­nitro­phen­yl)amide [H(2)NC(=O)NHC(NH(2))(2)](+)[N{C(6)H(2)(NO(2))(3)-2,4,6}(2)](−) (= guanylurea dipicryl­amide), was prepared as dark-red block-like crystals in 70% yield by salt-metathesis reaction between guanylurea sulfate and sodium dipicryl­amide. In the solid state, the new compound builds up an array of mutually linked guanylurea cations and dipicryl­amide anions. The crystal packing is dominated by an extensive network of N—H⋯O hydrogen bonds, resulting in a high density of 1.795 Mg m(−3), which makes the title compound a potential secondary explosive.
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spelling pubmed-41585452014-09-23 Crystal structure of the high-energy-density material guanylurea dipicryl­amide Deblitz, Raik Hrib, Cristian G. Hilfert, Liane Edelmann, Frank T. Acta Crystallogr Sect E Struct Rep Online Research Communications The title compound, 1-carbamoylguanidinium bis­(2,4,6-tri­nitro­phen­yl)amide [H(2)NC(=O)NHC(NH(2))(2)](+)[N{C(6)H(2)(NO(2))(3)-2,4,6}(2)](−) (= guanylurea dipicryl­amide), was prepared as dark-red block-like crystals in 70% yield by salt-metathesis reaction between guanylurea sulfate and sodium dipicryl­amide. In the solid state, the new compound builds up an array of mutually linked guanylurea cations and dipicryl­amide anions. The crystal packing is dominated by an extensive network of N—H⋯O hydrogen bonds, resulting in a high density of 1.795 Mg m(−3), which makes the title compound a potential secondary explosive. International Union of Crystallography 2014-07-31 /pmc/articles/PMC4158545/ /pubmed/25249869 http://dx.doi.org/10.1107/S1600536814017164 Text en © Deblitz et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Deblitz, Raik
Hrib, Cristian G.
Hilfert, Liane
Edelmann, Frank T.
Crystal structure of the high-energy-density material guanylurea dipicryl­amide
title Crystal structure of the high-energy-density material guanylurea dipicryl­amide
title_full Crystal structure of the high-energy-density material guanylurea dipicryl­amide
title_fullStr Crystal structure of the high-energy-density material guanylurea dipicryl­amide
title_full_unstemmed Crystal structure of the high-energy-density material guanylurea dipicryl­amide
title_short Crystal structure of the high-energy-density material guanylurea dipicryl­amide
title_sort crystal structure of the high-energy-density material guanylurea dipicryl­amide
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4158545/
https://www.ncbi.nlm.nih.gov/pubmed/25249869
http://dx.doi.org/10.1107/S1600536814017164
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AT edelmannfrankt crystalstructureofthehighenergydensitymaterialguanylureadipicrylamide

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