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catena-Poly[[[bis(1H-imidazole-κN (3))zinc(II)]-μ(2)-imidazol-1-ido-κ(2) N:N′] nitrate]
The title compound, {[Zn(C(3)H(3)N(2))(C(3)H(4)N(2))(2)]NO(3)}(n), is a one-dimensional coordination polymer along [01-1] with the Zn(II) atom coordinating to four imidazole/imidazolide rings. The Zn(II) atom has a regular tetrahedral geometry with the planes of the two monodentate imidazole rings...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4158546/ https://www.ncbi.nlm.nih.gov/pubmed/25249881 http://dx.doi.org/10.1107/S1600536814015232 |
Sumario: | The title compound, {[Zn(C(3)H(3)N(2))(C(3)H(4)N(2))(2)]NO(3)}(n), is a one-dimensional coordination polymer along [01-1] with the Zn(II) atom coordinating to four imidazole/imidazolide rings. The Zn(II) atom has a regular tetrahedral geometry with the planes of the two monodentate imidazole rings inclined to one another by 87.94 (17)°, while the planes of the bridging imidazolide rings are inclined to one another by 39.06 (17)°. In the crystal, the chains are linked via bifurcated N—H⋯(O,O) hydrogen bonds, forming sheets parallel to (001). These two-dimensional networks are linked via C—H⋯O hydrogen bonds and a C—H⋯π interaction, forming a three-dimensional structure. |
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