catena-Poly[[[bis­(1H-imidazole-κN (3))zinc(II)]-μ(2)-imidazol-1-ido-κ(2) N:N′] nitrate]

The title compound, {[Zn(C(3)H(3)N(2))(C(3)H(4)N(2))(2)]NO(3)}(n), is a one-dimensional coordination polymer along [01-1] with the Zn(II) atom coordinating to four imidazole/imidazolide rings. The Zn(II) atom has a regular tetra­hedral geometry with the planes of the two monodentate imidazole rings...

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Detalles Bibliográficos
Autores principales: Govindhan, Elumalai, Ganeshraja, A. S., Bhavana, B., Anbalagan, Krishnamoorthy, SubbiahPandi, Arunachalam
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4158546/
https://www.ncbi.nlm.nih.gov/pubmed/25249881
http://dx.doi.org/10.1107/S1600536814015232
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author Govindhan, Elumalai
Ganeshraja, A. S.
Bhavana, B.
Anbalagan, Krishnamoorthy
SubbiahPandi, Arunachalam
author_facet Govindhan, Elumalai
Ganeshraja, A. S.
Bhavana, B.
Anbalagan, Krishnamoorthy
SubbiahPandi, Arunachalam
author_sort Govindhan, Elumalai
collection PubMed
description The title compound, {[Zn(C(3)H(3)N(2))(C(3)H(4)N(2))(2)]NO(3)}(n), is a one-dimensional coordination polymer along [01-1] with the Zn(II) atom coordinating to four imidazole/imidazolide rings. The Zn(II) atom has a regular tetra­hedral geometry with the planes of the two monodentate imidazole rings inclined to one another by 87.94 (17)°, while the planes of the bridging imidazolide rings are inclined to one another by 39.06 (17)°. In the crystal, the chains are linked via bifurcated N—H⋯(O,O) hydrogen bonds, forming sheets parallel to (001). These two-dimensional networks are linked via C—H⋯O hydrogen bonds and a C—H⋯π inter­action, forming a three-dimensional structure.
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spelling pubmed-41585462014-09-23 catena-Poly[[[bis­(1H-imidazole-κN (3))zinc(II)]-μ(2)-imidazol-1-ido-κ(2) N:N′] nitrate] Govindhan, Elumalai Ganeshraja, A. S. Bhavana, B. Anbalagan, Krishnamoorthy SubbiahPandi, Arunachalam Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, {[Zn(C(3)H(3)N(2))(C(3)H(4)N(2))(2)]NO(3)}(n), is a one-dimensional coordination polymer along [01-1] with the Zn(II) atom coordinating to four imidazole/imidazolide rings. The Zn(II) atom has a regular tetra­hedral geometry with the planes of the two monodentate imidazole rings inclined to one another by 87.94 (17)°, while the planes of the bridging imidazolide rings are inclined to one another by 39.06 (17)°. In the crystal, the chains are linked via bifurcated N—H⋯(O,O) hydrogen bonds, forming sheets parallel to (001). These two-dimensional networks are linked via C—H⋯O hydrogen bonds and a C—H⋯π inter­action, forming a three-dimensional structure. International Union of Crystallography 2014-07-11 /pmc/articles/PMC4158546/ /pubmed/25249881 http://dx.doi.org/10.1107/S1600536814015232 Text en © Govindhan et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Govindhan, Elumalai
Ganeshraja, A. S.
Bhavana, B.
Anbalagan, Krishnamoorthy
SubbiahPandi, Arunachalam
catena-Poly[[[bis­(1H-imidazole-κN (3))zinc(II)]-μ(2)-imidazol-1-ido-κ(2) N:N′] nitrate]
title catena-Poly[[[bis­(1H-imidazole-κN (3))zinc(II)]-μ(2)-imidazol-1-ido-κ(2) N:N′] nitrate]
title_full catena-Poly[[[bis­(1H-imidazole-κN (3))zinc(II)]-μ(2)-imidazol-1-ido-κ(2) N:N′] nitrate]
title_fullStr catena-Poly[[[bis­(1H-imidazole-κN (3))zinc(II)]-μ(2)-imidazol-1-ido-κ(2) N:N′] nitrate]
title_full_unstemmed catena-Poly[[[bis­(1H-imidazole-κN (3))zinc(II)]-μ(2)-imidazol-1-ido-κ(2) N:N′] nitrate]
title_short catena-Poly[[[bis­(1H-imidazole-κN (3))zinc(II)]-μ(2)-imidazol-1-ido-κ(2) N:N′] nitrate]
title_sort catena-poly[[[bis­(1h-imidazole-κn (3))zinc(ii)]-μ(2)-imidazol-1-ido-κ(2) n:n′] nitrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4158546/
https://www.ncbi.nlm.nih.gov/pubmed/25249881
http://dx.doi.org/10.1107/S1600536814015232
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