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(E)-4-[7-(2,3-Di­hydro­thieno[3,4-b][1,4]dioxin-5-yl)-2,1,3-benzo­thia­diazol-4-yl]-2-[(neo­pentyl­imino)­meth­yl]phenol

In the title mol­ecule, C(24)H(23)N(3)O(3)S(2), the benzo­thia­diazole ring system is essentially planar, with an r.m.s. deviation of 0.020 (8) Å. The thio­phene and hy­droxy-substitiuted rings form dihedral angles of 23.43 (9) and 35.45 (9)°, respectively, with the benzo­thia­diazole ring system. A...

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Detalles Bibliográficos
Autores principales: Mitchell, Lauren A., Dinser, Jordan A., Holliday, Bradley J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4158547/
https://www.ncbi.nlm.nih.gov/pubmed/25249900
http://dx.doi.org/10.1107/S1600536814014883
Descripción
Sumario:In the title mol­ecule, C(24)H(23)N(3)O(3)S(2), the benzo­thia­diazole ring system is essentially planar, with an r.m.s. deviation of 0.020 (8) Å. The thio­phene and hy­droxy-substitiuted rings form dihedral angles of 23.43 (9) and 35.45 (9)°, respectively, with the benzo­thia­diazole ring system. An intra­molecular O—H⋯N hydrogen bond is observed. In the crystal, weak C—H⋯O hydrogen bonds and π–π stacking inter­actions [centroid–centroid distance = 3.880 (3) Å] link mol­ecules into chains along [100]. In addition, there are short S⋯S contacts [3.532 (3) Å] which link these chains, forming a two-dimensional network parallel to (010).