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7-Chloro-4-oxo-4H-chromene-3-carbaldehyde

In the title compound, C(10)H(5)ClO(3), a chlorinated 3-formyl­chromone derivative, all atoms are essentially coplanar (r.m.s. deviation = 0.0592 Å for all non-H atoms), with the largest deviation from the least-squares plane [0.1792 (19) Å] being for the chromone-ring carbonyl O atom. In the crysta...

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Detalles Bibliográficos
Autor principal: Ishikawa, Yoshinobu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4158550/
https://www.ncbi.nlm.nih.gov/pubmed/25249886
http://dx.doi.org/10.1107/S1600536814014925
Descripción
Sumario:In the title compound, C(10)H(5)ClO(3), a chlorinated 3-formyl­chromone derivative, all atoms are essentially coplanar (r.m.s. deviation = 0.0592 Å for all non-H atoms), with the largest deviation from the least-squares plane [0.1792 (19) Å] being for the chromone-ring carbonyl O atom. In the crystal, mol­ecules are linked through C—H⋯O hydrogen bonds to form tetrads, which are assembled by stacking inter­actions [centroid–centroid distance between the pyran rings = 3.823 (3) Å] and van der Waals contacts between the Cl atoms [Cl⋯Cl = 3.4483 (16) Å and C—Cl⋯Cl = 171.73 (7)°] into a three-dimensional architecture.