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Allylammonium hydrogen oxalate hemihydrate
In the title hydrated molecular salt, C(3)H(8)N(+)·C(2)HO(4) (−)·0.5H(2)O, the water O atom lies on a crystallographic twofold axis. The C=C—C—N torsion angle in the cation is 2.8 (3)° and the dihedral angle between the CO(2) and CO(2)H planes in the anion is 1.0 (4)°. In the crystal, the hydrogen...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4158551/ https://www.ncbi.nlm.nih.gov/pubmed/25249903 http://dx.doi.org/10.1107/S1600536814015190 |
Sumario: | In the title hydrated molecular salt, C(3)H(8)N(+)·C(2)HO(4) (−)·0.5H(2)O, the water O atom lies on a crystallographic twofold axis. The C=C—C—N torsion angle in the cation is 2.8 (3)° and the dihedral angle between the CO(2) and CO(2)H planes in the anion is 1.0 (4)°. In the crystal, the hydrogen oxalate ions are linked by O—H⋯O hydrogen bonds, generating [010] chains. The allylammonium cations bond to the chains through N—H⋯O and N—H⋯(O,O) hydrogen bonds. The water molecule accepts two N—H⋯O hydrogen bonds and makes two O—H⋯O hydrogen bonds. Together, the hydrogen bonds generate (100) sheets. |
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