The 1:1 charge-transfer complex dibenzo­tetra­thia­fulvalene–pyromellitic dianhydride (DBTTF–PMDA)

The title charge-transfer (CT) complex, C(10)H(2)O(6)·C(14)H(8)S(4), composed of donor dibenzo­tetra­thia­fulvalene (DBTTF) and acceptor pyromellitic dianhydride (PMDA), forms a mixed stacking pattern along the [-110] direction. The constituent mol­ecules occupy crystallographic inversion centers. T...

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Autores principales: Payne, Margaret E., Goetz, Katelyn P., Day, Cynthia S., Jurchescu, Oana D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4158552/
https://www.ncbi.nlm.nih.gov/pubmed/25249897
http://dx.doi.org/10.1107/S1600536814013324
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author Payne, Margaret E.
Goetz, Katelyn P.
Day, Cynthia S.
Jurchescu, Oana D.
author_facet Payne, Margaret E.
Goetz, Katelyn P.
Day, Cynthia S.
Jurchescu, Oana D.
author_sort Payne, Margaret E.
collection PubMed
description The title charge-transfer (CT) complex, C(10)H(2)O(6)·C(14)H(8)S(4), composed of donor dibenzo­tetra­thia­fulvalene (DBTTF) and acceptor pyromellitic dianhydride (PMDA), forms a mixed stacking pattern along the [-110] direction. The constituent mol­ecules occupy crystallographic inversion centers. They are nearly parallel and lie ca.3.41 Å from each other. The crystals exhibit a high degree of donor/acceptor overlap [88.20 (4)%] in the long direction of the DBTTF and PMDA mol­ecules as compared with 51.27 (5)% in the shortest direction of the mol­ecules.
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spelling pubmed-41585522014-09-23 The 1:1 charge-transfer complex dibenzo­tetra­thia­fulvalene–pyromellitic dianhydride (DBTTF–PMDA) Payne, Margaret E. Goetz, Katelyn P. Day, Cynthia S. Jurchescu, Oana D. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title charge-transfer (CT) complex, C(10)H(2)O(6)·C(14)H(8)S(4), composed of donor dibenzo­tetra­thia­fulvalene (DBTTF) and acceptor pyromellitic dianhydride (PMDA), forms a mixed stacking pattern along the [-110] direction. The constituent mol­ecules occupy crystallographic inversion centers. They are nearly parallel and lie ca.3.41 Å from each other. The crystals exhibit a high degree of donor/acceptor overlap [88.20 (4)%] in the long direction of the DBTTF and PMDA mol­ecules as compared with 51.27 (5)% in the shortest direction of the mol­ecules. International Union of Crystallography 2014-07-02 /pmc/articles/PMC4158552/ /pubmed/25249897 http://dx.doi.org/10.1107/S1600536814013324 Text en © Payne et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Payne, Margaret E.
Goetz, Katelyn P.
Day, Cynthia S.
Jurchescu, Oana D.
The 1:1 charge-transfer complex dibenzo­tetra­thia­fulvalene–pyromellitic dianhydride (DBTTF–PMDA)
title The 1:1 charge-transfer complex dibenzo­tetra­thia­fulvalene–pyromellitic dianhydride (DBTTF–PMDA)
title_full The 1:1 charge-transfer complex dibenzo­tetra­thia­fulvalene–pyromellitic dianhydride (DBTTF–PMDA)
title_fullStr The 1:1 charge-transfer complex dibenzo­tetra­thia­fulvalene–pyromellitic dianhydride (DBTTF–PMDA)
title_full_unstemmed The 1:1 charge-transfer complex dibenzo­tetra­thia­fulvalene–pyromellitic dianhydride (DBTTF–PMDA)
title_short The 1:1 charge-transfer complex dibenzo­tetra­thia­fulvalene–pyromellitic dianhydride (DBTTF–PMDA)
title_sort 1:1 charge-transfer complex dibenzo­tetra­thia­fulvalene–pyromellitic dianhydride (dbttf–pmda)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4158552/
https://www.ncbi.nlm.nih.gov/pubmed/25249897
http://dx.doi.org/10.1107/S1600536814013324
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