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Symmetrized Photoinitiated Electron Flow within the [Myoglobin:Cytochrome b(5)] Complex on Singlet and Triplet Time Scales: Energetics vs Dynamics
[Image: see text] We report here that photoinitiated electron flow involving a metal-substituted (M = Mg, Zn) myoglobin (Mb) and its physiological partner protein, cytochrome b(5) (cyt b(5)) can be “symmetrized”: the [Mb:cyt b(5)] complex stabilized by three D/E → K mutations on Mb (D44K/D60K/E85K,...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2014
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4160274/ https://www.ncbi.nlm.nih.gov/pubmed/25133915 http://dx.doi.org/10.1021/ja506388c |