Cargando…

Light-Induced N(2)O Production from a Non-heme Iron–Nitrosyl Dimer

[Image: see text] Two non-heme iron–nitrosyl species, [Fe(2)(N-Et-HPTB)(O(2)CPh)(NO)(2)](BF(4))(2) (1a) and [Fe(2)(N-Et-HPTB)(DMF)(2)(NO)(OH)](BF(4))(3) (2a), are characterized by FTIR and resonance Raman spectroscopy. Binding of NO is reversible in both complexes, which are prone to NO photolysis u...

Descripción completa

Detalles Bibliográficos
Autores principales: Jiang, Yunbo, Hayashi, Takahiro, Matsumura, Hirotoshi, Do, Loi H., Majumdar, Amit, Lippard, Stephen J., Moënne-Loccoz, Pierre
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4160282/
https://www.ncbi.nlm.nih.gov/pubmed/25158917
http://dx.doi.org/10.1021/ja504343t