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Pd-Catalyzed Aerobic Oxidative Coupling of Arenes: Evidence for Transmetalation between Two Pd(II)-Aryl Intermediates
[Image: see text] Pd-catalyzed aerobic oxidative coupling of arenes provides efficient access to biaryl compounds. The biaryl product forms via C–H activation of two arenes to afford a Pd(II)ArAr′ intermediate, which then undergoes C–C reductive elimination. The key Pd(II)ArAr′ intermediate could fo...
Autores principales: | Wang, Dian, Izawa, Yusuke, Stahl, Shannon S. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical
Society
2014
|
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4161672/ https://www.ncbi.nlm.nih.gov/pubmed/24965384 http://dx.doi.org/10.1021/ja505405u |
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