Stereochemistry and Mechanism of Enzymatic and Non-Enzymatic Hydrolysis of Benzylic sec-Sulfate Esters

The substrate scope of inverting alkylsulfatase Pisa1 was extended towards benzylic sec-sulfate esters by suppression of competing non-enzymatic autohydrolysis by addition of dimethyl sulfoxide as co-solvent. Detailed investigation of the mechanism of autohydrolysis in (18)O-labeled buffer by using...

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Detalles Bibliográficos
Autores principales: Toesch, Michael, Schober, Markus, Breinbauer, Rolf, Faber, Kurt
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2014
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4163651/
https://www.ncbi.nlm.nih.gov/pubmed/25232289
http://dx.doi.org/10.1002/ejoc.201402211

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4163651/
https://www.ncbi.nlm.nih.gov/pubmed/25232289
http://dx.doi.org/10.1002/ejoc.201402211

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