Stable Mixed-Valent Radicals from Platinum(II) Complexes of a Bis(dioxolene) Ligand

Three diplatinum(II) complexes [{PtL}(2)(μ-thea)] (H(4)thea=2,3,6,7-tetrahydroxy-9,10-dimethyl-9,10-dihydro-9,10-ethanoanthracene) have been prepared, with diphosphine or bipyridyl “L” co-ligands. One-electron oxidation of these complexes gave radical cations containing a mixed-valent [thea[Image: s...

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Detalles Bibliográficos
Autores principales: Loughrey, Jonathan J, Sproules, Stephen, McInnes, Eric J L, Hardie, Michaele J, Halcrow, Malcolm A
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2014
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4164269/
https://www.ncbi.nlm.nih.gov/pubmed/24488824
http://dx.doi.org/10.1002/chem.201304848

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4164269/
https://www.ncbi.nlm.nih.gov/pubmed/24488824
http://dx.doi.org/10.1002/chem.201304848

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