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Stable Mixed-Valent Radicals from Platinum(II) Complexes of a Bis(dioxolene) Ligand
Three diplatinum(II) complexes [{PtL}(2)(μ-thea)] (H(4)thea=2,3,6,7-tetrahydroxy-9,10-dimethyl-9,10-dihydro-9,10-ethanoanthracene) have been prepared, with diphosphine or bipyridyl “L” co-ligands. One-electron oxidation of these complexes gave radical cations containing a mixed-valent [thea[Image: s...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
WILEY-VCH Verlag
2014
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4164269/ https://www.ncbi.nlm.nih.gov/pubmed/24488824 http://dx.doi.org/10.1002/chem.201304848 |