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Spectroscopic and Computational Investigation of Iron(III) Cysteine Dioxygenase: Implications for the Nature of the Putative Superoxo-Fe(III) Intermediate

[Image: see text] Cysteine dioxygenase (CDO) is a mononuclear, non-heme iron-dependent enzyme that converts exogenous cysteine (Cys) to cysteine sulfinic acid using molecular oxygen. Although the complete catalytic mechanism is not yet known, several recent reports presented evidence for an Fe(III)-...

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Detalles Bibliográficos
Autores principales:	Blaesi, Elizabeth J., Fox, Brian G., Brunold, Thomas C.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2014
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4165443/ https://www.ncbi.nlm.nih.gov/pubmed/25093959 http://dx.doi.org/10.1021/bi500767x

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