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The Broken Ring: Reduced Aromaticity in Lys-Trp Cations and High pH Tautomer Correlates with Lower Quantum Yield and Shorter Lifetimes

[Image: see text] Several nonradiative processes compete with tryptophan fluorescence emission. The difficulty in spectral interpretation lies in associating specific molecular environmental features with these processes and thereby utilizing the fluorescence spectral data to identify the local envi...

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Detalles Bibliográficos
Autores principales: Eisenberg, Azaria Solomon, Juszczak, Laura J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4165537/
https://www.ncbi.nlm.nih.gov/pubmed/24882092
http://dx.doi.org/10.1021/jp503355h