Chiral phosphines in nucleophilic organocatalysis

This review discusses the tertiary phosphines possessing various chiral skeletons that have been used in asymmetric nucleophilic organocatalytic reactions, including annulations of allenes, alkynes, and Morita–Baylis–Hillman (MBH) acetates, carbonates, and ketenes with activated alkenes and imines,...

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Detalles Bibliográficos
Autores principales: Xiao, Yumei, Sun, Zhanhu, Guo, Hongchao, Kwon, Ohyun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2014
Materias:
Review
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4168899/
https://www.ncbi.nlm.nih.gov/pubmed/25246969
http://dx.doi.org/10.3762/bjoc.10.218
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author Xiao, Yumei
Sun, Zhanhu
Guo, Hongchao
Kwon, Ohyun
author_facet Xiao, Yumei
Sun, Zhanhu
Guo, Hongchao
Kwon, Ohyun
author_sort Xiao, Yumei
collection PubMed
description This review discusses the tertiary phosphines possessing various chiral skeletons that have been used in asymmetric nucleophilic organocatalytic reactions, including annulations of allenes, alkynes, and Morita–Baylis–Hillman (MBH) acetates, carbonates, and ketenes with activated alkenes and imines, allylic substitutions of MBH acetates and carbonates, Michael additions, γ-umpolung additions, and acylations of alcohols.
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spelling pubmed-41688992014-09-22 Chiral phosphines in nucleophilic organocatalysis Xiao, Yumei Sun, Zhanhu Guo, Hongchao Kwon, Ohyun Beilstein J Org Chem Review This review discusses the tertiary phosphines possessing various chiral skeletons that have been used in asymmetric nucleophilic organocatalytic reactions, including annulations of allenes, alkynes, and Morita–Baylis–Hillman (MBH) acetates, carbonates, and ketenes with activated alkenes and imines, allylic substitutions of MBH acetates and carbonates, Michael additions, γ-umpolung additions, and acylations of alcohols. Beilstein-Institut 2014-09-04 /pmc/articles/PMC4168899/ /pubmed/25246969 http://dx.doi.org/10.3762/bjoc.10.218 Text en Copyright © 2014, Xiao et al. https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Review
Xiao, Yumei
Sun, Zhanhu
Guo, Hongchao
Kwon, Ohyun
Chiral phosphines in nucleophilic organocatalysis
title Chiral phosphines in nucleophilic organocatalysis
title_full Chiral phosphines in nucleophilic organocatalysis
title_fullStr Chiral phosphines in nucleophilic organocatalysis
title_full_unstemmed Chiral phosphines in nucleophilic organocatalysis
title_short Chiral phosphines in nucleophilic organocatalysis
title_sort chiral phosphines in nucleophilic organocatalysis
topic Review
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4168899/
https://www.ncbi.nlm.nih.gov/pubmed/25246969
http://dx.doi.org/10.3762/bjoc.10.218
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AT sunzhanhu chiralphosphinesinnucleophilicorganocatalysis
AT guohongchao chiralphosphinesinnucleophilicorganocatalysis
AT kwonohyun chiralphosphinesinnucleophilicorganocatalysis

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