Isoxazolium N-ylides and 1-oxa-5-azahexa-1,3,5-trienes on the way from isoxazoles to 2H-1,3-oxazines

Theoretical and experimental studies of the reaction of isoxazoles with diazo compounds show that the formation of 2H-1,3-oxazines proceeds via the formation of (3Z)-1-oxa-5-azahexa-1,3,5-trienes which undergo a 6π-cyclization. The stationary points corresponding to the probable reaction intermediat...

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Detalles Bibliográficos
Autores principales: Khlebnikov, Alexander F, Novikov, Mikhail S, Gorbunova, Yelizaveta G, Galenko, Ekaterina E, Mikhailov, Kirill I, Pakalnis, Viktoriia V, Avdontceva, Margarita S
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2014
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4168923/
https://www.ncbi.nlm.nih.gov/pubmed/25246948
http://dx.doi.org/10.3762/bjoc.10.197

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4168923/
https://www.ncbi.nlm.nih.gov/pubmed/25246948
http://dx.doi.org/10.3762/bjoc.10.197

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