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A New Tool To Guide Halofunctionalization Reactions: The Halenium Affinity (HalA) Scale
[Image: see text] We introduce a previously unexplored parameter—halenium affinity (HalA)– as a quantitative descriptor of the bond strengths of various functional groups to halenium ions. The HalA scale ranks potential halenium ion acceptors based on their ability to stabilize a “free halenium ion”...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2014
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4183602/ https://www.ncbi.nlm.nih.gov/pubmed/25152188 http://dx.doi.org/10.1021/ja506889c |