Cargando…

Oxygen-Atom Transfer Reactivity of Axially Ligated Mn(V)–Oxo Complexes: Evidence for Enhanced Electrophilic and Nucleophilic Pathways

[Image: see text] Addition of anionic donors to the manganese(V)–oxo corrolazine complex Mn(V)(O)(TBP(8)Cz) has a dramatic influence on oxygen-atom transfer (OAT) reactivity with thioether substrates. The six-coordinate anionic [Mn(V)(O)(TBP(8)Cz)(X)](−) complexes (X = F(–), N(3)(–), OCN(–)) exhibit...

Descripción completa

Detalles Bibliográficos
Autores principales:	Neu, Heather M., Yang, Tzuhsiung, Baglia, Regina A., Yosca, Timothy H., Green, Michael T., Quesne, Matthew G., de Visser, Sam P., Goldberg, David P.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2014
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4183610/ https://www.ncbi.nlm.nih.gov/pubmed/25238495 http://dx.doi.org/10.1021/ja507177h

Ejemplares similares

Dramatic Influence of an Anionic Donor on the Oxygen-Atom Transfer Reactivity of a Mn(V)–Oxo Complex
por: Neu, Heather M, et al.
Publicado: (2014)

Activation of Electrophile/Nucleophile Pair by a Nucleophilic and Electrophilic Solvation in a S(N)Ar Reaction
por: Sánchez, Bruno, et al.
Publicado: (2018)

Electrophilic and nucleophilic pathways in ligand oxide mediated reactions of phenylsulfinylacetic acids with oxo(salen)chromium(V) complexes
por: Subramaniam, P., et al.
Publicado: (2016)

Activation of a High-Valent Manganese–Oxo Complex by a Nonmetallic Lewis Acid
por: Baglia, Regina A., et al.
Publicado: (2014)

Electrophilically Activated Nitroalkanes in Reactions With Carbon Based Nucleophiles
por: Aksenov, Nicolai A., et al.
Publicado: (2020)

Analogy of the Reactions of Aromatic and Aliphatic π-Electrophiles with Nucleophiles
por: Barbasiewicz, Michał, et al.
Publicado: (2023)

How Do Aromatic Nitro Compounds React with Nucleophiles? Theoretical Description Using Aromaticity, Nucleophilicity and Electrophilicity Indices
por: Błaziak, Kacper, et al.
Publicado: (2020)

Synthesis of Electrophiles Derived from Dimeric Aminoboranes and Assessing Their Utility in the Borylation of π Nucleophiles
por: Millet, Clément R. P., et al.
Publicado: (2022)

Chemical ligation of oligonucleotides using an electrophilic phosphorothioester
por: Maruyama, Hideto, et al.
Publicado: (2017)

1,3,2,5-Diazadiborinine featuring nucleophilic and electrophilic boron centres
por: Wu, Di, et al.
Publicado: (2015)

Metal-Free Regiodivergent Addition of Carbon Nucleophiles to α,β-Unsaturated Electrophiles
por: Spitz, Cédric, et al.
Publicado: (2017)

Reactive Sterol Electrophiles: Mechanisms of Formation and Reactions with Proteins and Amino Acid Nucleophiles()
por: Porter, Ned A., et al.
Publicado: (2020)

Dramatically Accelerated Selective Oxygen-Atom Transfer by a Nonheme Iron(IV)-Oxo Complex: Tuning of the First and Second Coordination Spheres
por: Widger, Leland R., et al.
Publicado: (2014)

Direct nucleophilic and electrophilic activation of alcohols using a unified boron-based organocatalyst scaffold
por: Rygus, Jason P. G., et al.
Publicado: (2023)

Profiling the reactivity of cyclic C-nucleophiles towards electrophilic sulfur in cysteine sulfenic acid
por: Gupta, Vinayak, et al.
Publicado: (2016)

Parallel evaluation of nucleophilic and electrophilic chemical probes for sulfenic acid: Reactivity, selectivity and biocompatibility
por: Shi, Yunlong, et al.
Publicado: (2021)

Replacing Conventional Carbon Nucleophiles with Electrophiles: Nickel-Catalyzed Reductive Alkylation of Aryl Bromides and Chlorides
por: Everson, Daniel A., et al.
Publicado: (2012)

Nucleophilic Attack of Azide at Electrophilic Azides: Formation of N(6) Units in Hexazene and Aminopentazole Derivatives
por: Banert, Klaus, et al.
Publicado: (2020)

Tuning the Nucleophilicity and Electrophilicity of Group 10 Elements through Substituent Effects: A DFT Study
por: Burguera, Sergi, et al.
Publicado: (2023)

Axially Ligated Mesohemins as Bio-Mimicking Catalysts for Atom Transfer Radical Polymerization
por: Fu, Liye, et al.
Publicado: (2019)

Catalytic Nucleophilic Fluorination of Secondary and Tertiary Propargylic Electrophiles with a Copper–N-Heterocyclic Carbene Complex
por: Cheng, Li-Jie, et al.
Publicado: (2015)

Nucleophilic and electrophilic cyclization of N-alkyne-substituted pyrrole derivatives: Synthesis of pyrrolopyrazinone, pyrrolotriazinone, and pyrrolooxazinone moieties
por: Yenice, Işıl, et al.
Publicado: (2017)

A DFT Study on the Molecular Mechanism of Additions of Electrophilic and Nucleophilic Carbenes to Non-Enolizable Cycloaliphatic Thioketones †
por: Mlostoń, Grzegorz, et al.
Publicado: (2021)

A nonheme peroxo-diiron(iii) complex exhibiting both nucleophilic and electrophilic oxidation of organic substrates
por: Török, Patrik, et al.
Publicado: (2021)

Direct Observation of a Nonheme Iron(IV)–Oxo Complex That Mediates Aromatic C–F Hydroxylation
por: Sahu, Sumit, et al.
Publicado: (2014)

Phenothiazinimides: Atom-Efficient Electrophilic Amination Reagents
por: Jin, Rongwei, et al.
Publicado: (2018)

Nucleophilic Substitution (S(N)2): Dependence on Nucleophile, Leaving Group, Central Atom, Substituents, and Solvent
por: Hamlin, Trevor A., et al.
Publicado: (2018)

Tandem addition of nucleophilic and electrophilic reagents to vinyl phosphinates: the stereoselective formation of organophosphorus compounds with congested tertiary carbons
por: Lin, Zhu, et al.
Publicado: (2023)

Turning sulfonyl and sulfonimidoyl fluoride electrophiles into sulfur(VI) radicals for alkene ligation
por: Wu, Xing, et al.
Publicado: (2023)

A theoretical study of the global and local electrophilicity, nucleophilicity, polarizability and QTAIM theory for calix[4]arene-gas interaction
por: Gassoumi, B., et al.
Publicado: (2020)

The flavin mononucleotide cofactor in α-hydroxyacid oxidases exerts its electrophilic/nucleophilic duality in control of the substrate-oxidation level
por: Lyu, Syue-Yi, et al.
Publicado: (2019)

Cu/Mn bimetallic catalysis enables carbonylative Suzuki–Miyaura coupling with unactivated alkyl electrophiles
por: Pye, Dominic R., et al.
Publicado: (2017)

Controlling the stereochemistry in 2-oxo-aldehyde-derived Ugi adducts through the cinchona alkaloid-promoted electrophilic fluorination
por: Wang, Yuqing, et al.
Publicado: (2020)

Oxygen transfer in electrophilic epoxidation probed by (17)O NMR: differentiating between oxidants and role of spectator metal oxo
por: Ehinger, Christian, et al.
Publicado: (2018)

Setting an Upper Limit on the Myoglobin Iron(IV)Hydroxide pK(a): Insight into Axial Ligand Tuning in Heme Protein Catalysis
por: Yosca, Timothy H., et al.
Publicado: (2014)

Highly efficient conversion of CO(2) to cyclic carbonates with a binary catalyst system in a microreactor: intensification of “electrophile–nucleophile” synergistic effect
por: Li, Ming-Ran, et al.
Publicado: (2018)

A Practical Method for the Preparation of (18)F-Labeled Aromatic Amino Acids from Nucleophilic [(18)F]Fluoride and Stannyl Precursors for Electrophilic Radiohalogenation
por: Zarrad, Fadi, et al.
Publicado: (2017)

Site-selective formation of an iron(iv)–oxo species at the more electron-rich iron atom of heteroleptic μ-nitrido diiron phthalocyanines
por: İşci, Ümit, et al.
Publicado: (2015)

Reaction of allene esters with Selectfluor/TMSX (X = I, Br, Cl) and Selectfluor/NH(4)SCN: Competing oxidative/electrophilic dihalogenation and nucleophilic/conjugate addition
por: Reddy, A Srinivas, et al.
Publicado: (2015)

Site-Specific, Intramolecular Cross-Linking of Pin1 Active Site Residues by the Lipid Electrophile 4-Oxo-2-nonenal
por: Aluise, Christopher D., et al.
Publicado: (2015)

Cannot write session to /tmp/vufind_sessions/sess_ds25m2pjnh4djjbo653jf7nr07