Cargando…

Decarboxylative Allylation of Amino Alkanoic Acids and Esters via Dual Catalysis

[Image: see text] A combination of photoredox and palladium catalysis has been employed to facilitate the room temperature decarboxylative allylation of recalcitrant α-amino and phenylacetic allyl esters. This operationally simple process produces CO(2) as the only byproduct and provides direct acce...

Descripción completa

Detalles Bibliográficos
Autores principales:	Lang, Simon B., O’Nele, Kathryn M., Tunge, Jon A.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2014
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4183636/ https://www.ncbi.nlm.nih.gov/pubmed/25228064 http://dx.doi.org/10.1021/ja508317j

Ejemplares similares

Organophotoredox/palladium dual catalytic decarboxylative Csp(3)–Csp(3) coupling of carboxylic acids and π-electrophiles
por: Cartwright, Kaitie C., et al.
Publicado: (2020)

Activation of Alcohols with Carbon Dioxide: Intermolecular Allylation of Weakly Acidic Pronucleophiles
por: Lang, Simon B., et al.
Publicado: (2014)

Nickel-catalyzed allylic defluorinative alkylation of trifluoromethyl alkenes with reductive decarboxylation of redox-active esters
por: Lu, Xi, et al.
Publicado: (2018)

Mechanistic dichotomy in the solvent dependent access to E vs. Z-allylic amines via decarboxylative vinylation of amino acids
por: Manna, Samir, et al.
Publicado: (2022)

Decarboxylative sp(3) C–N Coupling via Dual Copper/Photoredox Catalysis
por: Liang, Yufan, et al.
Publicado: (2018)

Dual nickel and Lewis acid catalysis for cross-electrophile coupling: the allylation of aryl halides with allylic alcohols
por: Jia, Xue-Gong, et al.
Publicado: (2017)

Decarboxylative Arylation of α-Amino Acids via Photoredox Catalysis: A One-Step Conversion of Biomass to Drug Pharmacophore
por: Zuo, Zhiwei, et al.
Publicado: (2014)

Palladium-Catalyzed Enantioselective Decarboxylative Allylic Alkylation of Cyclopentanones
por: Craig, Robert A., et al.
Publicado: (2015)

In Vitro and In Silico Anti-Picornavirus Triterpene Alkanoic Acid Ester from Saudi Collection of Rhazya stricta Decne
por: Abdel-Kader, Maged S., et al.
Publicado: (2023)

A General Strategy for the Asymmetric Preparation of α‐Stereogenic Allyl Silanes, Germanes, and Boronate Esters via Dual Copper Hydride‐ and Palladium‐Catalysis
por: Levi Knippel, James, et al.
Publicado: (2022)

Visible‐Light‐Mediated Decarboxylative Radical Additions to Vinyl Boronic Esters: Rapid Access to γ‐Amino Boronic Esters
por: Noble, Adam, et al.
Publicado: (2018)

Enantioselective synthesis of gem-disubstituted N-Boc diazaheterocycles via decarboxylative asymmetric allylic alkylation
por: Sun, Alexander W., et al.
Publicado: (2018)

Regio‐, Diastereo‐, and Enantioselective Decarboxylative Hydroaminoalkylation of Dienol Ethers Enabled by Dual Palladium/Photoredox Catalysis
por: Zheng, Jun, et al.
Publicado: (2022)

Decarboxylative Annulation of α-Amino Acids with γ-Nitroaldehydes
por: Kang, YoungKu, et al.
Publicado: (2016)

Palladium-Catalyzed Decarboxylative Asymmetric Allylic Alkylation of Thietane 1,1-Dioxides
por: Laidlaw, Gillian, et al.
Publicado: (2021)

Synthesis of Chiral, Enantiopure Allylic Amines by the Julia Olefination of α-Amino Esters
por: Benedetti, Fabio, et al.
Publicado: (2016)

Decarboxylative 1,4-carbocyanation of 1,3-enynes to access tetra-substituted allenes via copper/photoredox dual catalysis
por: Chen, Ya, et al.
Publicado: (2021)

Polyhydroxyalkanoate production in Pseudomonas putida from alkanoic acids of varying lengths
por: Sikkema, W. Dirk, et al.
Publicado: (2023)

α-Allyl-α-aryl α-Amino Esters in the Asymmetric Synthesis of Acyclic and Cyclic Amino Acid Derivatives by Alkene Metathesis
por: Curto, John M., et al.
Publicado: (2014)

Merging Photoredox and Nickel Catalysis: Decarboxylative Cross-Coupling of Carboxylic Acids with Vinyl Halides
por: Noble, Adam, et al.
Publicado: (2014)

Enantioselective Construction of Quaternary N-Heterocycles by Palladium-Catalyzed Decarboxylative Allylic Alkylation of Lactams
por: Behenna, Douglas C., et al.
Publicado: (2011)

Ruthenium-catalyzed decarboxylative C–S cross-coupling of carbonothioate: synthesis of allyl(aryl)sulfide
por: Zheng, Ren-Hua, et al.
Publicado: (2018)

Origins of Enhanced Enantioselectivity in the Pd-Catalyzed Decarboxylative Allylic Alkylation of N-Benzoyl Lactams ()
por: Cusumano, Alexander Q., et al.
Publicado: (2023)

Electrochemical Synthesis of Unnatural Amino Acids via Anodic Decarboxylation of N-Acetylamino Malonic Acid Derivatives
por: Koleda, Olesja, et al.
Publicado: (2023)

Tandem Palladium and Isothiourea Relay Catalysis: Enantioselective Synthesis of α-Amino Acid Derivatives via Allylic Amination and [2,3]-Sigmatropic Rearrangement
por: Spoehrle, Stéphanie S. M., et al.
Publicado: (2017)

Decarboxylative Cross-Electrophile Coupling of N-Hydroxyphthalimide Esters with Aryl Iodides
por: Huihui, Kierra M. M., et al.
Publicado: (2016)

Decarboxylative thiolation of redox-active esters to free thiols and further diversification
por: Cao, Tianpeng, et al.
Publicado: (2020)

Photocatalytic Decarboxylative Coupling of Aliphatic N‐hydroxyphthalimide Esters with Polyfluoroaryl Nucleophiles
por: Yi, Xiangli, et al.
Publicado: (2021)

Asymmetric Mannich Synthesis of α-Amino Esters by Anion-Binding Catalysis
por: Wasa, Masayuki, et al.
Publicado: (2014)

Regiocontrolled allylic functionalization of internal alkene via selenium-π-acid catalysis guided by boron substitution
por: Yang, Ling, et al.
Publicado: (2022)

Investigating the formation and diagnostic value of ω‐(o‐alkylphenyl)alkanoic acids in ancient pottery
por: Bondetti, M., et al.
Publicado: (2020)

Photoredox-catalyzed stereoselective alkylation of enamides with N-hydroxyphthalimide esters via decarboxylative cross-coupling reactions
por: Guo, Jing-Yu, et al.
Publicado: (2019)

Hydrocarbon Synthesis via Photoenzymatic Decarboxylation of Carboxylic Acids
por: Zhang, Wuyuan, et al.
Publicado: (2019)

Enantioselective Synthesis of α‐Aryl‐β(2)‐Amino‐Esters by Cooperative Isothiourea and Brønsted Acid Catalysis
por: Zhao, Feng, et al.
Publicado: (2021)

Biocatalytic synthesis of non-standard amino acids by a decarboxylative aldol reaction
por: Ellis, Jonathan M., et al.
Publicado: (2022)

Decarboxylative 1,3-dipolar cycloaddition of amino acids for the synthesis of heterocyclic compounds
por: Zhang, Xiaofeng, et al.
Publicado: (2023)

Microbial PolyHydroxyAlkanoate (PHA) Biopolymers—Intrinsically Natural
por: Mukherjee, Anindya, et al.
Publicado: (2023)

Photoredox-Catalyzed Giese Reactions: Decarboxylative Additions to Cyclic Vinylogous Amides and Esters
por: Dykstra, Kevin, et al.
Publicado: (2022)

Rh(III)-Catalyzed Decarboxylative Coupling of Acrylic Acids with Unsaturated Oxime Esters: Carboxylic Acids Serve as Traceless Activators
por: Neely, Jamie M., et al.
Publicado: (2014)

Asymmetric Synthesis of α-Allyl-α-Aryl α-Amino Acids by Tandem Alkylation/π-Allylation of α-Iminoesters
por: Curto, John M., et al.
Publicado: (2014)

Cannot write session to /tmp/vufind_sessions/sess_0hc7hfhq3pl97vsilvq5v4bfe3