Distance dependent charge separation and recombination in semiconductor/molecular catalyst systems for water splitting

The photoinduced reduction of three Co electrocatalysts immobilised on TiO(2) is 10(4) times faster than the reverse charge recombination. Both processes show an exponential dependence on the distance between the semiconductor and the catalytic core.

Detalles Bibliográficos
Autores principales: Reynal, Anna, Willkomm, Janina, Muresan, Nicoleta M., Lakadamyali, Fezile, Planells, Miquel, Reisner, Erwin, Durrant, James R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2014
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4183993/
https://www.ncbi.nlm.nih.gov/pubmed/25207748
http://dx.doi.org/10.1039/c4cc05143b
Descripción
Sumario:The photoinduced reduction of three Co electrocatalysts immobilised on TiO(2) is 10(4) times faster than the reverse charge recombination. Both processes show an exponential dependence on the distance between the semiconductor and the catalytic core.

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