Distance dependent charge separation and recombination in semiconductor/molecular catalyst systems for water splitting

The photoinduced reduction of three Co electrocatalysts immobilised on TiO(2) is 10(4) times faster than the reverse charge recombination. Both processes show an exponential dependence on the distance between the semiconductor and the catalytic core.

Detalles Bibliográficos
Autores principales: Reynal, Anna, Willkomm, Janina, Muresan, Nicoleta M., Lakadamyali, Fezile, Planells, Miquel, Reisner, Erwin, Durrant, James R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2014
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4183993/
https://www.ncbi.nlm.nih.gov/pubmed/25207748
http://dx.doi.org/10.1039/c4cc05143b
_version_ 1782337775113076736
author Reynal, Anna
Willkomm, Janina
Muresan, Nicoleta M.
Lakadamyali, Fezile
Planells, Miquel
Reisner, Erwin
Durrant, James R.
author_facet Reynal, Anna
Willkomm, Janina
Muresan, Nicoleta M.
Lakadamyali, Fezile
Planells, Miquel
Reisner, Erwin
Durrant, James R.
author_sort Reynal, Anna
collection PubMed
description The photoinduced reduction of three Co electrocatalysts immobilised on TiO(2) is 10(4) times faster than the reverse charge recombination. Both processes show an exponential dependence on the distance between the semiconductor and the catalytic core.
format Online
Article
Text
id pubmed-4183993
institution National Center for Biotechnology Information
language English
publishDate 2014
publisher Royal Society of Chemistry
record_format MEDLINE/PubMed
spelling pubmed-41839932014-10-17 Distance dependent charge separation and recombination in semiconductor/molecular catalyst systems for water splitting Reynal, Anna Willkomm, Janina Muresan, Nicoleta M. Lakadamyali, Fezile Planells, Miquel Reisner, Erwin Durrant, James R. Chem Commun (Camb) Chemistry The photoinduced reduction of three Co electrocatalysts immobilised on TiO(2) is 10(4) times faster than the reverse charge recombination. Both processes show an exponential dependence on the distance between the semiconductor and the catalytic core. Royal Society of Chemistry 2014-10-28 2014-09-10 /pmc/articles/PMC4183993/ /pubmed/25207748 http://dx.doi.org/10.1039/c4cc05143b Text en This journal is © The Royal Society of Chemistry 2014 http://creativecommons.org/licenses/by/3.0/ This is an Open Access article distributed under the terms of the Creative Commons Attribution 3.0 Unported License (http://creativecommons.org/licenses/by/3.0/) which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
spellingShingle Chemistry
Reynal, Anna
Willkomm, Janina
Muresan, Nicoleta M.
Lakadamyali, Fezile
Planells, Miquel
Reisner, Erwin
Durrant, James R.
Distance dependent charge separation and recombination in semiconductor/molecular catalyst systems for water splitting
title Distance dependent charge separation and recombination in semiconductor/molecular catalyst systems for water splitting
title_full Distance dependent charge separation and recombination in semiconductor/molecular catalyst systems for water splitting
title_fullStr Distance dependent charge separation and recombination in semiconductor/molecular catalyst systems for water splitting
title_full_unstemmed Distance dependent charge separation and recombination in semiconductor/molecular catalyst systems for water splitting
title_short Distance dependent charge separation and recombination in semiconductor/molecular catalyst systems for water splitting
title_sort distance dependent charge separation and recombination in semiconductor/molecular catalyst systems for water splitting
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4183993/
https://www.ncbi.nlm.nih.gov/pubmed/25207748
http://dx.doi.org/10.1039/c4cc05143b
work_keys_str_mv AT reynalanna distancedependentchargeseparationandrecombinationinsemiconductormolecularcatalystsystemsforwatersplitting
AT willkommjanina distancedependentchargeseparationandrecombinationinsemiconductormolecularcatalystsystemsforwatersplitting
AT muresannicoletam distancedependentchargeseparationandrecombinationinsemiconductormolecularcatalystsystemsforwatersplitting
AT lakadamyalifezile distancedependentchargeseparationandrecombinationinsemiconductormolecularcatalystsystemsforwatersplitting
AT planellsmiquel distancedependentchargeseparationandrecombinationinsemiconductormolecularcatalystsystemsforwatersplitting
AT reisnererwin distancedependentchargeseparationandrecombinationinsemiconductormolecularcatalystsystemsforwatersplitting
AT durrantjamesr distancedependentchargeseparationandrecombinationinsemiconductormolecularcatalystsystemsforwatersplitting

Ejemplares similares