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Crystal structure of (E)-1(anthracen-9-ylmethylidene)[2-(morpholin-4-yl)eth­yl]amine

The title compound, C(21)H(22)N(2)O, crystallizes with two independent mol­ecules in the asymmetric unit. In both mol­ecules, the anthracene ring systems are almost planar, with maximum deviations of 0.071 (8) and 0.028 (7) Å, and make dihedral angles of 73.4 (2) and 73.3 (2)° with the least-squares...

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Detalles Bibliográficos
Autores principales: Atioğlu, Zeliha, Akkurt, Mehmet, Jarrahpour, Aliasghar, Chermahini, Mehdi Mohammadi, Büyükgüngör, Orhan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186061/
https://www.ncbi.nlm.nih.gov/pubmed/25309217
http://dx.doi.org/10.1107/S1600536814018807
Descripción
Sumario:The title compound, C(21)H(22)N(2)O, crystallizes with two independent mol­ecules in the asymmetric unit. In both mol­ecules, the anthracene ring systems are almost planar, with maximum deviations of 0.071 (8) and 0.028 (7) Å, and make dihedral angles of 73.4 (2) and 73.3 (2)° with the least-squares planes formed by the four C atoms of the morpholine rings, which adopt a chair conformation. An intra­molecular C—H⋯π inter­action occurs. In the crystal, the packing is stabilized by weak C—H⋯O hydrogen bonds, which connect pairs of molecules into parallel to the c axis, and C—H⋯π inter­actions.