Crystal structure of (E)-1(anthracen-9-ylmethylidene)[2-(morpholin-4-yl)eth­yl]amine

The title compound, C(21)H(22)N(2)O, crystallizes with two independent mol­ecules in the asymmetric unit. In both mol­ecules, the anthracene ring systems are almost planar, with maximum deviations of 0.071 (8) and 0.028 (7) Å, and make dihedral angles of 73.4 (2) and 73.3 (2)° with the least-squares...

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Autores principales: Atioğlu, Zeliha, Akkurt, Mehmet, Jarrahpour, Aliasghar, Chermahini, Mehdi Mohammadi, Büyükgüngör, Orhan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186061/
https://www.ncbi.nlm.nih.gov/pubmed/25309217
http://dx.doi.org/10.1107/S1600536814018807
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author Atioğlu, Zeliha
Akkurt, Mehmet
Jarrahpour, Aliasghar
Chermahini, Mehdi Mohammadi
Büyükgüngör, Orhan
author_facet Atioğlu, Zeliha
Akkurt, Mehmet
Jarrahpour, Aliasghar
Chermahini, Mehdi Mohammadi
Büyükgüngör, Orhan
author_sort Atioğlu, Zeliha
collection PubMed
description The title compound, C(21)H(22)N(2)O, crystallizes with two independent mol­ecules in the asymmetric unit. In both mol­ecules, the anthracene ring systems are almost planar, with maximum deviations of 0.071 (8) and 0.028 (7) Å, and make dihedral angles of 73.4 (2) and 73.3 (2)° with the least-squares planes formed by the four C atoms of the morpholine rings, which adopt a chair conformation. An intra­molecular C—H⋯π inter­action occurs. In the crystal, the packing is stabilized by weak C—H⋯O hydrogen bonds, which connect pairs of molecules into parallel to the c axis, and C—H⋯π inter­actions.
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spelling pubmed-41860612014-10-12 Crystal structure of (E)-1(anthracen-9-ylmethylidene)[2-(morpholin-4-yl)eth­yl]amine Atioğlu, Zeliha Akkurt, Mehmet Jarrahpour, Aliasghar Chermahini, Mehdi Mohammadi Büyükgüngör, Orhan Acta Crystallogr Sect E Struct Rep Online Data Reports The title compound, C(21)H(22)N(2)O, crystallizes with two independent mol­ecules in the asymmetric unit. In both mol­ecules, the anthracene ring systems are almost planar, with maximum deviations of 0.071 (8) and 0.028 (7) Å, and make dihedral angles of 73.4 (2) and 73.3 (2)° with the least-squares planes formed by the four C atoms of the morpholine rings, which adopt a chair conformation. An intra­molecular C—H⋯π inter­action occurs. In the crystal, the packing is stabilized by weak C—H⋯O hydrogen bonds, which connect pairs of molecules into parallel to the c axis, and C—H⋯π inter­actions. International Union of Crystallography 2014-08-23 /pmc/articles/PMC4186061/ /pubmed/25309217 http://dx.doi.org/10.1107/S1600536814018807 Text en © Atioğlu et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Atioğlu, Zeliha
Akkurt, Mehmet
Jarrahpour, Aliasghar
Chermahini, Mehdi Mohammadi
Büyükgüngör, Orhan
Crystal structure of (E)-1(anthracen-9-ylmethylidene)[2-(morpholin-4-yl)eth­yl]amine
title Crystal structure of (E)-1(anthracen-9-ylmethylidene)[2-(morpholin-4-yl)eth­yl]amine
title_full Crystal structure of (E)-1(anthracen-9-ylmethylidene)[2-(morpholin-4-yl)eth­yl]amine
title_fullStr Crystal structure of (E)-1(anthracen-9-ylmethylidene)[2-(morpholin-4-yl)eth­yl]amine
title_full_unstemmed Crystal structure of (E)-1(anthracen-9-ylmethylidene)[2-(morpholin-4-yl)eth­yl]amine
title_short Crystal structure of (E)-1(anthracen-9-ylmethylidene)[2-(morpholin-4-yl)eth­yl]amine
title_sort crystal structure of (e)-1(anthracen-9-ylmethylidene)[2-(morpholin-4-yl)eth­yl]amine
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186061/
https://www.ncbi.nlm.nih.gov/pubmed/25309217
http://dx.doi.org/10.1107/S1600536814018807
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