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Crystal structure of 2-phenyl-2λ(4),3-ditelluratetracyclo[5.5.2.0(4,13).0(10,14)]tetradeca-1(12),4,6,10,13-pentaen-2-ylium trifluoromethanesulfonate
In the title compound, C(18)H(13)Te(2) (+)·CF(3)O(3)S(−), the Te(II) atom of the cation and one O atom of the trifluoromethanesulfonate counter-ion form a close-to-linear Te—Te—O system, with a Te—Te—O angle of 172.3 (1)° and a Te—O distance of 2.816 (5) Å, which may suggest the presence of a thr...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2014
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186063/ https://www.ncbi.nlm.nih.gov/pubmed/25309192 http://dx.doi.org/10.1107/S1600536814018170 |
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| author | Diamond, Louise M. Slawin, Alexandra M. Z. Woollins, J. Derek |
| author_facet | Diamond, Louise M. Slawin, Alexandra M. Z. Woollins, J. Derek |
| author_sort | Diamond, Louise M. |
| collection | PubMed |
| description | In the title compound, C(18)H(13)Te(2) (+)·CF(3)O(3)S(−), the Te(II) atom of the cation and one O atom of the trifluoromethanesulfonate counter-ion form a close-to-linear Te—Te—O system, with a Te—Te—O angle of 172.3 (1)° and a Te—O distance of 2.816 (5) Å, which may suggest the presence of a three-centre–four-electron (3c–4e) bond. Secondary Te⋯O interactions [3.003 (4) and 3.016 (4) Å], involving the second Te(II) atom of the binuclear molecule, are also noted, resulting in a supramolecular layer in the bc plane. |
| format | Online Article Text |
| id | pubmed-4186063 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2014 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-41860632014-10-12 Crystal structure of 2-phenyl-2λ(4),3-ditelluratetracyclo[5.5.2.0(4,13).0(10,14)]tetradeca-1(12),4,6,10,13-pentaen-2-ylium trifluoromethanesulfonate Diamond, Louise M. Slawin, Alexandra M. Z. Woollins, J. Derek Acta Crystallogr Sect E Struct Rep Online Data Reports In the title compound, C(18)H(13)Te(2) (+)·CF(3)O(3)S(−), the Te(II) atom of the cation and one O atom of the trifluoromethanesulfonate counter-ion form a close-to-linear Te—Te—O system, with a Te—Te—O angle of 172.3 (1)° and a Te—O distance of 2.816 (5) Å, which may suggest the presence of a three-centre–four-electron (3c–4e) bond. Secondary Te⋯O interactions [3.003 (4) and 3.016 (4) Å], involving the second Te(II) atom of the binuclear molecule, are also noted, resulting in a supramolecular layer in the bc plane. International Union of Crystallography 2014-08-13 /pmc/articles/PMC4186063/ /pubmed/25309192 http://dx.doi.org/10.1107/S1600536814018170 Text en © Diamond et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Data Reports Diamond, Louise M. Slawin, Alexandra M. Z. Woollins, J. Derek Crystal structure of 2-phenyl-2λ(4),3-ditelluratetracyclo[5.5.2.0(4,13).0(10,14)]tetradeca-1(12),4,6,10,13-pentaen-2-ylium trifluoromethanesulfonate |
| title | Crystal structure of 2-phenyl-2λ(4),3-ditelluratetracyclo[5.5.2.0(4,13).0(10,14)]tetradeca-1(12),4,6,10,13-pentaen-2-ylium trifluoromethanesulfonate |
| title_full | Crystal structure of 2-phenyl-2λ(4),3-ditelluratetracyclo[5.5.2.0(4,13).0(10,14)]tetradeca-1(12),4,6,10,13-pentaen-2-ylium trifluoromethanesulfonate |
| title_fullStr | Crystal structure of 2-phenyl-2λ(4),3-ditelluratetracyclo[5.5.2.0(4,13).0(10,14)]tetradeca-1(12),4,6,10,13-pentaen-2-ylium trifluoromethanesulfonate |
| title_full_unstemmed | Crystal structure of 2-phenyl-2λ(4),3-ditelluratetracyclo[5.5.2.0(4,13).0(10,14)]tetradeca-1(12),4,6,10,13-pentaen-2-ylium trifluoromethanesulfonate |
| title_short | Crystal structure of 2-phenyl-2λ(4),3-ditelluratetracyclo[5.5.2.0(4,13).0(10,14)]tetradeca-1(12),4,6,10,13-pentaen-2-ylium trifluoromethanesulfonate |
| title_sort | crystal structure of 2-phenyl-2λ(4),3-ditelluratetracyclo[5.5.2.0(4,13).0(10,14)]tetradeca-1(12),4,6,10,13-pentaen-2-ylium trifluoromethanesulfonate |
| topic | Data Reports |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186063/ https://www.ncbi.nlm.nih.gov/pubmed/25309192 http://dx.doi.org/10.1107/S1600536814018170 |
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