Crystal structure of N-(1-allyl-3-chloro-1H-indazol-5-yl)-4-methyl­benzene­sulfonamide

The 3-chloro-1H-indazole system in the title mol­ecule, C(17)H(16)ClN(3)O(2)S, is almost planar, with the largest deviation from the mean plane being 0.029 (2) Å for one of the N atoms. This system is nearly perpendicular to the allyl chain, as indicated by the C—C—N—N torsion angle of −90.1 (6)° be...

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Autores principales: Chicha, Hakima, Rakib, El Mostapha, Chigr, Mohamed, Saadi, Mohamed, El Ammari, Lahcen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186064/
https://www.ncbi.nlm.nih.gov/pubmed/25309215
http://dx.doi.org/10.1107/S1600536814018194
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author Chicha, Hakima
Rakib, El Mostapha
Chigr, Mohamed
Saadi, Mohamed
El Ammari, Lahcen
author_facet Chicha, Hakima
Rakib, El Mostapha
Chigr, Mohamed
Saadi, Mohamed
El Ammari, Lahcen
author_sort Chicha, Hakima
collection PubMed
description The 3-chloro-1H-indazole system in the title mol­ecule, C(17)H(16)ClN(3)O(2)S, is almost planar, with the largest deviation from the mean plane being 0.029 (2) Å for one of the N atoms. This system is nearly perpendicular to the allyl chain, as indicated by the C—C—N—N torsion angle of −90.1 (6)° between them. The allyl group is split into two fragments, the major component has a site occupancy of 0.579 (7). The indazole system makes a dihedral angle of 47.53 (10)° with the plane through the benzene ring. In the crystal, mol­ecules are connected by N—H⋯O and C—H⋯O hydrogen bonds, forming a three-dimensional network.
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spelling pubmed-41860642014-10-12 Crystal structure of N-(1-allyl-3-chloro-1H-indazol-5-yl)-4-methyl­benzene­sulfonamide Chicha, Hakima Rakib, El Mostapha Chigr, Mohamed Saadi, Mohamed El Ammari, Lahcen Acta Crystallogr Sect E Struct Rep Online Data Reports The 3-chloro-1H-indazole system in the title mol­ecule, C(17)H(16)ClN(3)O(2)S, is almost planar, with the largest deviation from the mean plane being 0.029 (2) Å for one of the N atoms. This system is nearly perpendicular to the allyl chain, as indicated by the C—C—N—N torsion angle of −90.1 (6)° between them. The allyl group is split into two fragments, the major component has a site occupancy of 0.579 (7). The indazole system makes a dihedral angle of 47.53 (10)° with the plane through the benzene ring. In the crystal, mol­ecules are connected by N—H⋯O and C—H⋯O hydrogen bonds, forming a three-dimensional network. International Union of Crystallography 2014-08-23 /pmc/articles/PMC4186064/ /pubmed/25309215 http://dx.doi.org/10.1107/S1600536814018194 Text en © Chicha et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Chicha, Hakima
Rakib, El Mostapha
Chigr, Mohamed
Saadi, Mohamed
El Ammari, Lahcen
Crystal structure of N-(1-allyl-3-chloro-1H-indazol-5-yl)-4-methyl­benzene­sulfonamide
title Crystal structure of N-(1-allyl-3-chloro-1H-indazol-5-yl)-4-methyl­benzene­sulfonamide
title_full Crystal structure of N-(1-allyl-3-chloro-1H-indazol-5-yl)-4-methyl­benzene­sulfonamide
title_fullStr Crystal structure of N-(1-allyl-3-chloro-1H-indazol-5-yl)-4-methyl­benzene­sulfonamide
title_full_unstemmed Crystal structure of N-(1-allyl-3-chloro-1H-indazol-5-yl)-4-methyl­benzene­sulfonamide
title_short Crystal structure of N-(1-allyl-3-chloro-1H-indazol-5-yl)-4-methyl­benzene­sulfonamide
title_sort crystal structure of n-(1-allyl-3-chloro-1h-indazol-5-yl)-4-methyl­benzene­sulfonamide
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186064/
https://www.ncbi.nlm.nih.gov/pubmed/25309215
http://dx.doi.org/10.1107/S1600536814018194
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