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Crystal structure of (E)-1-methyl-2-[2-(2-methoxphen­yl)ethen­yl]-4-nitro-1H-imidazole

In the asymmetric unit of the title compound, C(13)H(13)N(3)O(3), the 2-(2-methoxphen­yl)ethenyl unit is connected to the methyl-nitro­imidazole 1-methyl-4-nitro-1H-imidazole moiety. The mol­ecule is quasi-planar and the planes of the two rings form a dihedral angle of 0.92 (11)°. The crystal packin...

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Autores principales: Alliouche, Hayette, Bouraiou, Abdelmalek, Bouacida, Sofiane, Merazig, Hocine, Belfaitah, Ali
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186069/
https://www.ncbi.nlm.nih.gov/pubmed/25309283
http://dx.doi.org/10.1107/S1600536814017206
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author Alliouche, Hayette
Bouraiou, Abdelmalek
Bouacida, Sofiane
Merazig, Hocine
Belfaitah, Ali
author_facet Alliouche, Hayette
Bouraiou, Abdelmalek
Bouacida, Sofiane
Merazig, Hocine
Belfaitah, Ali
author_sort Alliouche, Hayette
collection PubMed
description In the asymmetric unit of the title compound, C(13)H(13)N(3)O(3), the 2-(2-methoxphen­yl)ethenyl unit is connected to the methyl-nitro­imidazole 1-methyl-4-nitro-1H-imidazole moiety. The mol­ecule is quasi-planar and the planes of the two rings form a dihedral angle of 0.92 (11)°. The crystal packing can be described as layers parallel to the (011) plane, stabilized by inter­molecular C—H⋯O hydrogen bonding, resulting in the formation of an infinite three-dimensional network linking these layers. Strong π–π stacking inter­actions are observed, viz. benzene–benzene, imidazole–imidazole and benzene–imidazole rings, with centroid–centroid distances of 3.528 (2), 3.457 (2) and 3.544 (2) Å, respectively. Intensity statistics indicated twinning by non-merohedry, with refined weighs of the twin components of 0.3687:0.6313.
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spelling pubmed-41860692014-10-12 Crystal structure of (E)-1-methyl-2-[2-(2-methoxphen­yl)ethen­yl]-4-nitro-1H-imidazole Alliouche, Hayette Bouraiou, Abdelmalek Bouacida, Sofiane Merazig, Hocine Belfaitah, Ali Acta Crystallogr Sect E Struct Rep Online Data Reports In the asymmetric unit of the title compound, C(13)H(13)N(3)O(3), the 2-(2-methoxphen­yl)ethenyl unit is connected to the methyl-nitro­imidazole 1-methyl-4-nitro-1H-imidazole moiety. The mol­ecule is quasi-planar and the planes of the two rings form a dihedral angle of 0.92 (11)°. The crystal packing can be described as layers parallel to the (011) plane, stabilized by inter­molecular C—H⋯O hydrogen bonding, resulting in the formation of an infinite three-dimensional network linking these layers. Strong π–π stacking inter­actions are observed, viz. benzene–benzene, imidazole–imidazole and benzene–imidazole rings, with centroid–centroid distances of 3.528 (2), 3.457 (2) and 3.544 (2) Å, respectively. Intensity statistics indicated twinning by non-merohedry, with refined weighs of the twin components of 0.3687:0.6313. International Union of Crystallography 2014-08-01 /pmc/articles/PMC4186069/ /pubmed/25309283 http://dx.doi.org/10.1107/S1600536814017206 Text en © Alliouche et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Alliouche, Hayette
Bouraiou, Abdelmalek
Bouacida, Sofiane
Merazig, Hocine
Belfaitah, Ali
Crystal structure of (E)-1-methyl-2-[2-(2-methoxphen­yl)ethen­yl]-4-nitro-1H-imidazole
title Crystal structure of (E)-1-methyl-2-[2-(2-methoxphen­yl)ethen­yl]-4-nitro-1H-imidazole
title_full Crystal structure of (E)-1-methyl-2-[2-(2-methoxphen­yl)ethen­yl]-4-nitro-1H-imidazole
title_fullStr Crystal structure of (E)-1-methyl-2-[2-(2-methoxphen­yl)ethen­yl]-4-nitro-1H-imidazole
title_full_unstemmed Crystal structure of (E)-1-methyl-2-[2-(2-methoxphen­yl)ethen­yl]-4-nitro-1H-imidazole
title_short Crystal structure of (E)-1-methyl-2-[2-(2-methoxphen­yl)ethen­yl]-4-nitro-1H-imidazole
title_sort crystal structure of (e)-1-methyl-2-[2-(2-methoxphen­yl)ethen­yl]-4-nitro-1h-imidazole
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186069/
https://www.ncbi.nlm.nih.gov/pubmed/25309283
http://dx.doi.org/10.1107/S1600536814017206
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