Crystal structure of chlorido­penta­kis(dimethyl sulfoxide-κO)chromium(III) dichloride

In the complex cation of the title salt, [CrCl(C(2)H(6)OS)(5)]Cl(2), the Cr(III) ion is coordinated by one chloride ligand and five O atoms from dimethyl sulfoxide (DMSO) ligands, leading to a slightly distorted octa­hedral coordination environment [O—Cr—O angles range from 86.69 (16) to 92.87 (16)°...

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Detalles Bibliográficos
Autores principales: Son, Kyung-sun, Woo, Jeong Oh, Kim, Namhun, Kang, Sung Kwon
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186071/
https://www.ncbi.nlm.nih.gov/pubmed/25309174
http://dx.doi.org/10.1107/S1600536814015852
Descripción
Sumario:In the complex cation of the title salt, [CrCl(C(2)H(6)OS)(5)]Cl(2), the Cr(III) ion is coordinated by one chloride ligand and five O atoms from dimethyl sulfoxide (DMSO) ligands, leading to a slightly distorted octa­hedral coordination environment [O—Cr—O angles range from 86.69 (16) to 92.87 (16)°]. In the crystal, complex cations are arranged in hexa­gonally packed rows parallel to [010], with the chloride counter-anions situated in between. The inter­actions between cations and anions are mainly ionic in nature.

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