Crystal structure of chlorido­penta­kis(dimethyl sulfoxide-κO)chromium(III) dichloride

In the complex cation of the title salt, [CrCl(C(2)H(6)OS)(5)]Cl(2), the Cr(III) ion is coordinated by one chloride ligand and five O atoms from dimethyl sulfoxide (DMSO) ligands, leading to a slightly distorted octa­hedral coordination environment [O—Cr—O angles range from 86.69 (16) to 92.87 (16)°...

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Autores principales: Son, Kyung-sun, Woo, Jeong Oh, Kim, Namhun, Kang, Sung Kwon
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186071/
https://www.ncbi.nlm.nih.gov/pubmed/25309174
http://dx.doi.org/10.1107/S1600536814015852
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author Son, Kyung-sun
Woo, Jeong Oh
Kim, Namhun
Kang, Sung Kwon
author_facet Son, Kyung-sun
Woo, Jeong Oh
Kim, Namhun
Kang, Sung Kwon
author_sort Son, Kyung-sun
collection PubMed
description In the complex cation of the title salt, [CrCl(C(2)H(6)OS)(5)]Cl(2), the Cr(III) ion is coordinated by one chloride ligand and five O atoms from dimethyl sulfoxide (DMSO) ligands, leading to a slightly distorted octa­hedral coordination environment [O—Cr—O angles range from 86.69 (16) to 92.87 (16)°]. In the crystal, complex cations are arranged in hexa­gonally packed rows parallel to [010], with the chloride counter-anions situated in between. The inter­actions between cations and anions are mainly ionic in nature.
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spelling pubmed-41860712014-10-12 Crystal structure of chlorido­penta­kis(dimethyl sulfoxide-κO)chromium(III) dichloride Son, Kyung-sun Woo, Jeong Oh Kim, Namhun Kang, Sung Kwon Acta Crystallogr Sect E Struct Rep Online Data Reports In the complex cation of the title salt, [CrCl(C(2)H(6)OS)(5)]Cl(2), the Cr(III) ion is coordinated by one chloride ligand and five O atoms from dimethyl sulfoxide (DMSO) ligands, leading to a slightly distorted octa­hedral coordination environment [O—Cr—O angles range from 86.69 (16) to 92.87 (16)°]. In the crystal, complex cations are arranged in hexa­gonally packed rows parallel to [010], with the chloride counter-anions situated in between. The inter­actions between cations and anions are mainly ionic in nature. International Union of Crystallography 2014-08-01 /pmc/articles/PMC4186071/ /pubmed/25309174 http://dx.doi.org/10.1107/S1600536814015852 Text en © Son et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Son, Kyung-sun
Woo, Jeong Oh
Kim, Namhun
Kang, Sung Kwon
Crystal structure of chlorido­penta­kis(dimethyl sulfoxide-κO)chromium(III) dichloride
title Crystal structure of chlorido­penta­kis(dimethyl sulfoxide-κO)chromium(III) dichloride
title_full Crystal structure of chlorido­penta­kis(dimethyl sulfoxide-κO)chromium(III) dichloride
title_fullStr Crystal structure of chlorido­penta­kis(dimethyl sulfoxide-κO)chromium(III) dichloride
title_full_unstemmed Crystal structure of chlorido­penta­kis(dimethyl sulfoxide-κO)chromium(III) dichloride
title_short Crystal structure of chlorido­penta­kis(dimethyl sulfoxide-κO)chromium(III) dichloride
title_sort crystal structure of chlorido­penta­kis(dimethyl sulfoxide-κo)chromium(iii) dichloride
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186071/
https://www.ncbi.nlm.nih.gov/pubmed/25309174
http://dx.doi.org/10.1107/S1600536814015852
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